2375-30-6

Basic information

• Product Name: pentafluorosulfanyl isocyanate
• Synonyms: pentafluorosulfanyl isocyanate
• CAS NO: 2375-30-6
• Molecular Weight: 169.075
• Mol File: 2375-30-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: pentafluorosulfanyl isocyanate(CAS DataBase Reference)
• NIST Chemistry Reference: pentafluorosulfanyl isocyanate(2375-30-6)
• EPA Substance Registry System: pentafluorosulfanyl isocyanate(2375-30-6)

Safety Data

• Hazardous Substances Data: 2375-30-6(Hazardous Substances Data)

Upstream product

• 2375-35-1 SF₅NHCF₃ 
• 65-85-0 benzoic acid 
• 89573-63-7 1,2-Ethanediyl Bis<(pentafluorosulfanyl)carbamate> 
• 89590-17-0 S-Phenyl (Pentafluorosulfanyl)thiocarbamate 
• 81439-23-8 Phenyl (Pentafluorosulfanyl)carbamate 
• 89606-92-8 S-Methyl (Pentafluorosulfanyl)thiocarbamate 
• 89590-14-7 N-Pentafluorosulfanyl-methyl carbamate 

Downstream Products

• 90598-14-4 1-(4-Methoxyphenyl)-N-(pentafluorosulfanyl)methanimine 
• 90598-10-0 N'-(Pentafluorosulfanyl)-N,N-diphenylurea 
• 81439-23-8 Phenyl (Pentafluorosulfanyl)carbamate 
• 90598-05-3 1,1'-(1,4-Phenylene)bis<3-(pentafluorosulfanyl)urea> 
• 90598-17-7 N-Methyl-N'-(pentafluorosulfanyl)-N-phenylformamidine 
• 90597-97-0 1,4-Phenylene Bis<(pentafluorosulfanyl)carbamate> 
• 90597-98-1 4-Hydroxyphenyl (Pentafluorosulfanyl)carbamate 
• 90598-04-2 N-(Pentafluorosulfanyl)-N'-phenylurea 
• 89590-17-0 S-Phenyl (Pentafluorosulfanyl)thiocarbamate 
• 90598-06-4 1,1'-(Methylenedi-4,1-phenylene)bis<3-(pentafluorosulfanyl)urea> 
• 58982-75-5 N-(Pentafluorosulfanyl)-1-phenylmethanimine 
• 90598-13-3 1-(4-Methylphenyl)-N-(pentafluorosulfanyl)methanimine 
• 136397-68-7 N-Pentafluorosulfanyl-<2-(2,4,6-trinitrophenyl)ethyl>carbamate 
• 136397-67-6 N-Pentafluorosulfanyl-2,4,6-trinitrobenzyl carbamate 

Relevant articles and documents

ACYLATIONS OF PENTAFLUOROSULFANYLAMINE, SF5NH2. PART II. REACTIONS OF N-PENTAFLUOROSULFANYLCARBAMYLFLUORIDE, SF5NHC(O)F, AND N-PENTAFLUOROSULFANYLPERFLUOROSUCCINIMIDE,

The carbamyl fluoride SF5NHC(O)F reacts with both H2O and H2S to give the urea (SF5NH)2CO.Evidence supports that this reaction proceeds through a mechanism involving dehydrofluorination; whereas, the reagents PhLi and PCl5 serve only to dehydrofluorinate SF5NHC(O)F.The ring of the cyclic imide can be readily opened by nucleophiles to give products such as SF5NHC(O)CF2CF2C(O)OH, SF5NHC(O)CF2CF2C(O)NH2, and SF5NHC(O)CF2CF2C(O)OCH3.Attempts to prepare analogous six- and seven-membered cyclic imides failed; however, mono- (SF5NHC(O)(CF2)3,4C(O)F) and disubstituted products (SF5NHC(O)(CF2)3,4C(O)NHSF5) were formed.The amide-acid fluorides are easily hydrolyzed by atmospheric moisture to the amide-acids SF5NHC(O)(CF2)3,4C(O)OH.