2377-53-9Relevant academic research and scientific papers
Copper-mediated radical cross-coupling reaction of 2,2-dichloro-1,1,1- trifluoroethane (HCFC-123) with phenols or thiophenols
Tang, Xiao-Jun,Chen, Qing-Yun
supporting information, p. 6214 - 6217 (2013/02/22)
A copper-mediated cross-coupling reaction between HCFC-123 and phenols or thiophenols has been achieved. It is found that diethyl amine, which serves as both the activator and ligand of copper, plays a key role in this reaction. Two possible radical involved processes are proposed for the reaction mechanism.
