237736-40-2

Basic information

• Product Name: (+)-endo-Bicyclo[3.2.1]oct-3-en-2-ol
• CAS NO: 237736-40-2
• Molecular Weight: 124.183
• Mol File: 237736-40-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (+)-endo-Bicyclo[3.2.1]oct-3-en-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-endo-Bicyclo[3.2.1]oct-3-en-2-ol(237736-40-2)
• EPA Substance Registry System: (+)-endo-Bicyclo[3.2.1]oct-3-en-2-ol(237736-40-2)

Safety Data

• Hazardous Substances Data: 237736-40-2(Hazardous Substances Data)

Upstream product

• 108-05-4 vinyl acetate 
• 32222-49-4 endo-bicyclo<3.2.1>oct-3-en-2-ol 
• 39762-77-1 endo-bicyclo<3.2.1.>oct-3-en-2-yl acetate 
• 237752-68-0 (+)-4-Acetoxybicyclo[3.2.1]oct-2-ene 
• 497-38-1 2-norbornanone 
• 57722-40-4 2-trimethylsilyloxybicyclo<2.2.1>hept-2-ene 
• 99957-00-3 Trimethyl-((1S,2S,4S,5R)-tricyclo[3.2.1.0^2,4]oct-2-yloxy)-silane 
• 3212-77-9 bicyclo<3.2.1>oct-3-en-2-one 

Downstream Products

• 319906-82-6 (1R,4S,5S)-4-Benzyloxymethyl-bicyclo[3.2.1]octan-2-one 

Relevant articles and documents

Diastereodivergent synthesis of the C9-cyclopentanone chiral building blocks

Diastereodivergent synthesis the C9-cyclopentanone chiral building block, serving as the non-tryptamine moiety of the Corynanthe type indole alkaloids and the related natural products, and its diastereomer has been developed from racemic norcamphor by employing lipase-mediated resolution via an allylic acetate intermediate having a bicyclo[3.2.1]octane framework. A potential of the latter diastereomer has been demonstrated by its conversion into (-)-semburin, a monoterpene isolated from Swertia japonica previously and obtained from the C9-block.