237757-95-8

Basic information

• Product Name: 2,5-bis(acetyl methyl)-1,4-bis(dodecyloxy)benzene
• Synonyms: 2,5-bis(acetyl methyl)-1,4-bis(dodecyloxy)benzene
• CAS NO: 237757-95-8
• Molecular Weight: 590.885
• Mol File: 237757-95-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,5-bis(acetyl methyl)-1,4-bis(dodecyloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-bis(acetyl methyl)-1,4-bis(dodecyloxy)benzene(237757-95-8)
• EPA Substance Registry System: 2,5-bis(acetyl methyl)-1,4-bis(dodecyloxy)benzene(237757-95-8)

Safety Data

• Hazardous Substances Data: 237757-95-8(Hazardous Substances Data)

Upstream product

• 127-08-2 potassium acetate 
• 122996-59-2 1,4-bis(bromomethyl)-2,5-bis-(dodecyloxy)benzene 
• 3230-09-9 1,4-bis-dodecyloxy-benzene 
• 143-15-7 1-dodecylbromide 
• 127-09-3 sodium acetate 

Downstream Products

• 123415-45-2 1,4-di(n-dodecyloxy)benzene-2,5-dicarboxaldehyde 
• 237757-97-0 2,5-bis(hydroxymethyl)-1,4-bis(dodecyloxy)benzene 

Relevant articles and documents

Effect of the bulkiness of the end functional amide groups on the optical, gelation, and morphological properties of oligo(p-phenylenevinylene) π-gelators

Herein, we describe the role of end functional groups in the self-assembly of amide-functionalized oligo(p-phenylenevinylene) (OPV) gelators with different end-groups. The interplay between hydrogen-bonding and π-stacking interactions was controlled by the bulkiness of the end functional groups, thereby resulting in aggregates of different types, which led to the gelation of a wide range of solvents. The variable-temperature UV/Vis absorption and fluorescence spectroscopic features of gelators with small end-groups revealed the formation of 1D H-type aggregates in CHCl3. However, under fast cooling in toluene, 1D H-type aggregates were formed, whereas slow cooling resulted in 2D H-type aggregates. OPV amide with bulky dendritic end-group formed hydrogen-bonded random aggregates in toluene and a morphology transition from vesicles into fibrous aggregates was observed in THF. Interestingly, the presence of bulky end-group enhanced fluorescence in the xerogel state and aggregation in polar solvents. The difference between the aggregation properties of OPV amides with small and bulky end-groups allowed the preparation of self-assembled structures with distinct morphological and optical features. Buying in bulk: OPV amides with small end-groups self-assemble into 2D/1D aggregates in toluene and 1D aggregates in CHCl3. Bulky end-groups impede fluorescence quenching in the self-assembled state by blocking π-stacking and facilitate morphological transition in THF.

Green-blue photoluminescence from a novel silicon-containing alternating copolymer

A novel silicon-containing copolymer with an alternating structure, poly[(5-decyldimethylsilyl-1,3-phenylenevinylene)-alt-(2,5-didodecyloxy-1,4-phen ylenevinylene)], is synthesized through the Wittig reaction. The polymer is a promising green-blue emissiv