2381-19-3

Usage

Uses

Used in Environmental Analysis:
3-METHYLBENZO[C]PHENANTHRENE STANDARD SOLUTION is used as a calibration and validation tool for analytical methods in environmental analysis. It helps ensure accurate and reliable results in the detection and quantification of 3-methylbenzo[c]phenanthrene in air, water, and soil samples.
Used in Industrial Applications:
3-METHYLBENZO[C]PHENANTHRENE STANDARD SOLUTION is used as a reference material in industrial applications to monitor and control the presence of PAHs in various products and processes. This helps in maintaining safety and quality standards in the industry.
Used in Research and Development:
3-METHYLBENZO[C]PHENANTHRENE STANDARD SOLUTION is used as a research tool in the development of new analytical methods and techniques for the detection and quantification of PAHs. It aids in understanding the behavior and properties of 3-methylbenzo[c]phenanthrene and other PAHs in different environmental and industrial conditions.

InChI:InChI=1/C19H14/c1-13-6-11-18-16(12-13)10-9-15-8-7-14-4-2-3-5-17(14)19(15)18/h2-12H,1H3

Upstream product

• 52988-15-5 6-methyl-2-(bromomethyl)naphthalene 
• 100-52-7 benzaldehyde 
• 91-22-5 quinoline 
• 108-38-3 m-xylene 
• 1047647-69-7 1,1-difluoro-2-(2-phenylethyl)-4-(3-methylphenyl)but-1-ene 
• 1047647-78-8 3-methyl-5,6,7,8-tetrahydrobenzo[c]phenanthrene 
• 97080-36-9 3-(4-Methyl-benzhydryl)-glutarsaeure 
• 94377-88-5 3-(4-Methyl-benzhydryl)-glutaronitril 
• 98801-51-5 5,6,6a,7,8,12b-Hexahydro-3-methyl-benzophenanthrendion-(5,8) 
• 38503-47-8 (E)-2-(3-methylstyryl)naphthalene 
• 63216-65-9 2-methyl-6-styrylnaphtalene 

Downstream Products

• 89441-52-1 bromure de 3-triphenylphosphoniomethylbenzophenanthrene 

Relevant academic research and scientific papers

Air-Driven Potassium Iodide-Mediated Oxidative Photocyclization of Stilbene Derivatives

A new method has been developed for the potassium iodide-mediated oxidative photocyclization of stilbene derivatives. Compared with conventional iodine-mediated oxidative photocyclization reactions, this new method requires shorter reaction times and affords cyclized products in yields of 45-97%. This reaction proceeds with a catalytic amount of potassium iodide and works in an air-driven manner without the addition of an external scavenger. The radical-mediated oxidative photocyclization of stilbene derivatives using TEMPO was also investigated.

Domino Friedel-crafts-type cyclizations of difluoroalkenes promoted by the α-cation-stabilizing effect of fluorine: An efficient method for synthesizing angular PAHs

In order to synthesize polycyclic aromatic hydrocarbons with nonlinear arrangements (angular PAHs), acid-promoted domino cyclizations of 1,1-difluoroalk-1-enes and 1,1-difluoroalka-1,3-dienes were studied. 1,1-Difluoroalkenes, each bearing two aryl substituents, were regioselectively protonated with FSO3H·SbF5 to generate fluorine-stabilized carbocations, which readily underwent domino Friedel-Crafts-type cyclizations to give carbocycles based on 6/n/m/6 ring systems (n,m=5-7) in good to high yields. Protonation of 1,1-difluoroalka-1,3- dienes took place at their electron-rich methylene (CH2) carbon atoms in the presence of milder acids such as camphorsulfonic acid and trifluoromethanesulfonic acid. Domino cyclizations of the resulting fluorine-stabilized allylic carbocations afford carbocycles based on 6/6/6/6 or 6/6/5/6 ring systems in high yields.

Efficient helicene synthesis: Friedel-crafts-type cyclization of 1,1-difluoro-1-alkenes

(Chemical Equation Presented) The unique properties of fluorine substituents, leaving groups that also stabilize an a carbocation, are exploited in a high-yielding synthesis of substituted [4]- to [6]helicenes in three or four steps from commercially available compounds: Two fused benzene rings are constructed in the title reaction of readily prepared 1,1-difluoro-1-alkenes containing two aryl groups followed by dehydrogenation (see scheme).

SYNTHESE PHOTOCHIMIQUE D'HYDROCARBURES POLYCYCLIQUES AROMATIQUES ET ETUDE EN RMN-1H DES PROTONS DE BAIE. EFFECTS DE SOLVANT SPECIFIQUES ET EFFECTS NUCLEAIRES OVERHAUSER.

"Photochemical synthesis of polycyclic aromatic hydrocarbons and NMR-1H study of bay protons.Specific solvent effects and nuclear Overhauser effects".Dinaphthoanthracene (4a),9-bromo-dinaphthoanthracene (4b), 9-methyldinaphthoanthracene (4c), benzonaphthochrysene (7), benzonaphthoanthracene (3), naphthochrysene (9) and dibenzonaphthochrysene (12) have been synthesized by the photocyclodehydrogenation of 1,2-diarylethylenes (5,8) and bis (arylvinyl)arenes (6,10).The NMR study has been mainly focused on the bay protons involved in specific solvent effects Table 4) and nuclear Overhauser effects (Table 5).