239125-36-1

Basic information

• Product Name: (S)-5-benzoyloxymethyl-3-oximinotetrahydrofuran-2-one
• Synonyms: (S)-5-benzoyloxymethyl-3-oximinotetrahydrofuran-2-one
• CAS NO: 239125-36-1
• Molecular Weight: 249.223
• Mol File: 239125-36-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-5-benzoyloxymethyl-3-oximinotetrahydrofuran-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-5-benzoyloxymethyl-3-oximinotetrahydrofuran-2-one(239125-36-1)
• EPA Substance Registry System: (S)-5-benzoyloxymethyl-3-oximinotetrahydrofuran-2-one(239125-36-1)

Safety Data

• Hazardous Substances Data: 239125-36-1(Hazardous Substances Data)

Upstream product

• 32780-07-7 (S)-5-(benzoyloxymethyl)tetrahydrofuran-2-one 
• 239125-33-8 (S)-5-benzoyloxymethyl-3-dimethylaminomethylenetetrahydrofuran-2-one 

Relevant articles and documents

Stereoselective amination of 5-substituted γ-lactones and γ-lactams - A convenient route for the preparation of 5-substituted (3S,5S)-3- acetylaminotetrahydrofuran-2-ones and (3S,5S)-3-acetylaminopyrrolidin-2-ones

5-Substituted (S)-tetrahydrofuran-2-ones (1a,b) and (S)pyrrolidin-2- ones (1c,d) were transformed in three steps, by treatment with tert- butoxybis(dimethylamino)methane (Bredereck's reagent), followed by nitrosation and stereoselective catalytic hydrogenation, into the corresponding 5-substituted (3S,5S)-3-acetylaminotetrahydrofuran-2-ones (4a,b) and (3S,5S)-3-acetylaminopyrrolidin-2-ones (4c,d).