23939-49-3Relevant academic research and scientific papers
Oxidation reactions in segmented and continuous flow chemical processing using an N -(tert -Butyl)phenylsulfinimidoyl chloride monolith
Lange, Heiko,Capener, Matthew J.,Jones, Alexander X.,Smith, Catherine J.,Nikbin, Nikzad,Baxendale, Ian R.,Ley, Steven V.
supporting information; experimental part, p. 869 - 873 (2011/06/21)
A supported version of N-(tert-butyl)phenylsulfinim-idoyl chloride on a monolithic material is described, which can be incorporated into a flow chemical processing arrangement to oxidise a variety of substrates in both stoichiometric and catalytic processes to yield products in high yields and in high purity after in-line workup. Georg Thieme Verlag Stuttgart.
Stoichiometric functionalization of gold nanoparticles in solution through a free radical polymerization approach
Krueger, Christian,Agarwal, Seema,Greiner, Andreas
, p. 2710 - 2711 (2008/09/20)
A new simple concept for the stoichiometrical functionalization of nanoparticles based on free radical polymerization of vinyl protected nanoparticles is presented. To demonstrate this concept 2-bis(4-vinylphenyl)disulfane was synthesized and used in the synthesis of gold nanoparticles, leading to 4-vinylthiophenol functionalized nanoparticles. Simple free radical polymerization of these particles initiated by 4,4′-azobis-(4-cyanopentanoic acid) delivered nanoparticles with a singlecarboxyl group. These monofunctionalized gold nanoparticles were utilized for chemical preparation of gold nanoparticle dimers as well as for construction of gold nanoparticle arrays via binding to polyallylamine. Copyright
Synthesis and characterization of aryl thioacetyl styrene monomers: towards a new generation of SERS-active polymers
Al-Hourani, Baker Jawabrah,Bravo-Vasquez, Juan P.,Hermann High,Fenniri, Hicham
, p. 9144 - 9147 (2008/09/17)
A new family of thioacetyl styrene derivatives was synthesized in good isolated yields for the preparation of spectroscopically-encoded SERS-active polymers.
Bromine catalyzed conversion of S-tert-butyl groups into versatile and, for self-assembly processes accessible, acetyl-protected thiols
Blaszczyk, Alfred,Elbing, Mark,Mayor, Marcel
, p. 2722 - 2724 (2007/10/03)
The facile and efficient conversion of a tert-butyl protecting group to an acetyl protecting group for thiols by catalytic amounts of bromine in acetyl chloride and the presence of acetic acid has been developed. The fairly mild reaction conditions are of
Synthesis and testing of new end-functionalized oligomers for molecular electronics
Flatt, Austen K.,Dirk, Shawn M.,Henderson, Jay C.,Shen, Dwanleen E.,Su, Jie,Reed, Mark A.,Tour, James M.
, p. 8555 - 8570 (2007/10/03)
Several new classes of oligomers have been synthesized with functionalities designed to aid in the understanding of molecular device behavior, specifically when molecules are interfaced between proximal electronic probes. The compounds synthesized are series of azobenzenes, bipyridines and oligo(phenylene vinylene)s that bear acetyl-protected thiols for ultimate attachment to metallic surfaces. Some initial electrochemical and solid-state test results are also reported.
