239446-17-4Relevant academic research and scientific papers
Influence of the chiral auxiliary on the stereoselectivity of the S(RN)1 C-alkylation of 2-nitropropionate anions
Nouguier, Robert,Beraud, Valerie,Vanelle, Patrice,Crozet, Michel P.
, p. 5013 - 5014 (1999)
A series of carbohydrate-derived 2-nitropropionate anions was reacted with p-nitrobenzyl chloride under S(RN)1 reactions conditions, the diastereomeric ratios were moderate, but increased when the carbohydrate moiety was replaced by the more bulky 8-phenylmenthol.
