Influence of the chiral auxiliary on the stereoselectivity of the S(RN)1 C-alkylation of 2-nitropropionate anions

DOI: 10.1016/S0040-4039(99)00935-1

Source and publish data:

Tetrahedron Letters p. 5013 - 5014 (1999)

Update date:2022-09-26

Topics:

Authors:

Nouguier, Robert

Beraud, Valerie

Vanelle, Patrice

Crozet, Michel P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(99)00935-1

A series of carbohydrate-derived 2-nitropropionate anions was reacted with p-nitrobenzyl chloride under S(RN)1 reactions conditions, the diastereomeric ratios were moderate, but increased when the carbohydrate moiety was replaced by the more bulky 8-phenylmenthol.

Full text of DOI:10.1016/S0040-4039(99)00935-1

Products guided by the article

Product name:2-Bromo-propionic acid (2R,4aR,6S,7R,8S,8aR)-8-benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester

Cas No:239446-17-4

R&D Labs maybe for 239446-17-4

Taizhou Elitechemie MediPharma Technology Co.,Ltd.

Contact:+86-523-86810021

Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
Dragon Chemical Co., Ltd.

Contact:0571-

Address:zhejing
Shanghai UCHEM Inc.

Contact:+86-21-56338808

Address:799 Dunhuang Road, Putuo
NEM CHEMICAL CO.，LTD

website:http://www.NEM.COM.CN

Contact:+86-393-4411771

Address:The west section of shengli Road,Puyang,Henan Province,China
HEZE KINGVOLT CHEMICAL CO., LTD

Contact:86-573-82118911

Address:Juancheng Industry Park

Relevant to this article

Doi:10.1016/S0040-4020(01)82917-3
(1969)
Phosphine and isonitrile complexes of η⁵-tetramethylcyclopentadienylrhodium chlorides; crystal structures of (η⁵-C₅Me₄H)RhCl₂(PPh ₂R) (R = Ph or C₆F₅)

Doi:10.1016/S0022-328X(99)00151-5
(1999)
Investigations of a nucleophilic alaninol synthon derived from serine

Doi:10.1021/ja9906249
(1999)
Inducing Social Self-Sorting in Organic Cages To Tune The Shape of The Internal Cavity

Doi:10.1002/anie.202007571
(2020)
Stereochemistry at phosphorus of the reaction catalyzed by myo-inositol monophosphatase

Doi:10.1021/jm011056m
(2002)
Transition-metal-free carbonylation of aryl halides with arylboronic acids by utilizing stoichiometric CHCl₃ as the carbon monoxide-precursor

Doi:10.1039/c9gc00598f
(2019)

Article Doi