239475-34-4Relevant academic research and scientific papers
Metal complexes of biologically important ligands.
Ederer, Theodor,Sünkel, Karlheinz,Beck, Wolfgang
, p. 1202 - 1206 (1999)
The addition of [Ph2C=NCHCO2Me]- to [(C6H7)Fe(CO)3]+, [(C7H9)Fe(CO)3]+, [(C7H7)M(CO)3]+ (M = Cr, Mo) and [(C2H4)Re(CO)5]+ gives derivatives of α-amino acids with organometallic side chains. The structure of [(η4-C6H7)CH(N=CPh2)CO 2Me]Fe(CO)3 was determined by X-ray diffraction. From the adduct of [Ph2C=NCHCO2Me]- and [(C7H7)Mo(CO)3]+ the Schiff base of a new unnatural examina acid, Ph2C=NCH(C7H7)CO2Me, was obtained.
