23995-20-2

Basic information

• Product Name: 2-methylsulfanyl-3-phenyl-5,6-dihydro-4H-pyrrolo[1,2-b]pyrazole
• Synonyms: 2-methylsulfanyl-3-phenyl-5,6-dihydro-4H-pyrrolo[1,2-b]pyrazole
• CAS NO: 23995-20-2
• Molecular Weight: 230.334
• Mol File: 23995-20-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-methylsulfanyl-3-phenyl-5,6-dihydro-4H-pyrrolo[1,2-b]pyrazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methylsulfanyl-3-phenyl-5,6-dihydro-4H-pyrrolo[1,2-b]pyrazole(23995-20-2)
• EPA Substance Registry System: 2-methylsulfanyl-3-phenyl-5,6-dihydro-4H-pyrrolo[1,2-b]pyrazole(23995-20-2)

Safety Data

• Hazardous Substances Data: 23995-20-2(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 1626400-87-0 C₁₃H₁₄N₄S 
• 24595-58-2 5-phenylpent-4-yn-1-ol 
• 1626400-84-7 C₁₃H₁₆N₄S 
• 28525-69-1 (4E)-5-phenyl-4-pentenoic acid 

Downstream Products

• 10183-74-1 withasomnine 

Relevant articles and documents

5-(Methylthio)tetrazoles as versatile synthons in the stereoselective synthesis of polycyclic pyrazolines via photoinduced intramolecular nitrile imine-alkene 1,3-dipolar cycloaddition

A key thioether substituent in readily accessible 2-alkyl-5-(methylthio) tetrazoles enables facile photoinduced denitrogenation and intramolecular nitrile imine 1,3-dipolar cycloaddition to afford a wide range of polycyclic pyrazoline products with excellent diastereoselectivity. The methylthio group red-shifts the UV absorbance of the tetrazole, obviating the requirement in all previous substrate systems for at least one aryl substituent, and can subsequently be converted into a variety of other functionalities. This synthetic platform has been applied to the concise total syntheses of the alkaloid natural products (±)-newbouldine and withasomnine. This journal is the Partner Organisations 2014.