2400-01-3

Basic information

• Product Name: Tridecane, 7-phenyl-
• Synonyms: Tridecane, 7-phenyl-;7-Phenyltridecane
• CAS NO: 2400-01-3
• Molecular Formula: C₁₉H₃₂
• Molecular Weight: 260.46
• Mol File: 2400-01-3.mol

Chemical Properties

• Melting Point: -28.2°C
• Boiling Point: 338.72°C (estimate)
• Flash Point: 155.7°C
• Appearance: /
• Density: 0.8528
• Vapor Pressure: 0.000179mmHg at 25°C
• Refractive Index: 1.4931
• CAS DataBase Reference: Tridecane, 7-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Tridecane, 7-phenyl-(2400-01-3)
• EPA Substance Registry System: Tridecane, 7-phenyl-(2400-01-3)

Safety Data

• Hazardous Substances Data: 2400-01-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C19H32/c1-3-5-7-10-14-18(15-11-8-6-4-2)19-16-12-9-13-17-19/h9,12-13,16-18H,3-8,10-11,14-15H2,1-2H3

Upstream product

• 71-43-2 benzene 
• 100-52-7 benzaldehyde 
• 638-45-9 1-Iodohexane 
• 6005-98-7 7-hydroxy-7-phenyl-tridecane 
• 614-54-0 1-phenylheptan-1-ol 
• 111-71-7 heptanal 
• 111-25-1 1-bromo-hexane 
• 104388-23-0 (1-Methylselanyl-heptyl)-benzene 
• 591-51-5 phenyllithium 

Relevant articles and documents

Nickel-catalyzed reductive deoxygenation of diverse C-O bond-bearing functional groups

We report a catalytic method for the direct deoxygenation of various C-O bond-containing functional groups. Using a Ni(II) pre-catalyst and silane reducing agent, alcohols, epoxides, and ethers are reduced to the corresponding alkane. Unsaturated species including aldehydes and ketones are also deoxygenated via initial formation of an intermediate silylated alcohol. The reaction is chemoselective for C(sp3)-O bonds, leaving amines, anilines, aryl ethers, alkenes, and nitrogen-containing heterocycles untouched. Applications toward catalytic deuteration, benzyl ether deprotection, and the valorization of biomass-derived feedstocks demonstrate some of the practical aspects of this methodology.

Nickel(II)-catalyzed carbon-carbon bond formation reaction of functionalized organozinc reagents with aromatic aldehydes

In the presence of a silylating reagent and catalytic amount of Ni(acac)2, organozinc halides reacted with aromatic aldehydes to give the corresponding dialkylation products in good to excellent yields under mild conditions.

Process for the production of phenylalkanes using a hydrocarbon fraction that is obtained from the Fischer-Tropsch process

A process for the production of phenylalkanes comprising a reaction for alkylation of at least one aromatic compound by at least one hydrocarbon fraction that is directly obtained from the Fischer-Tropsch process comprising linear olefins that have 9 to 16 carbon atoms per molecule and oxygenated compounds is described. Said alkylation reaction is carried out in a catalytic reactor that contains at least one reaction zone that comprises at least one acidic solid catalyst, and said hydrocarbon fraction does not undergo any purification treatment prior to its introduction into said reaction zone.

Novel Synthetic Route to Aryl Alkanes from Aromatic Aldehydes and Ketones. Novel Geminal Dialkylation of the Carbonyl Group of Aromatic Aldehydes and Ketones

Benzyl-lithiums, readily available from benzyl methyl selenides and alkyl-lithiums, are efficiently alkylated; this reaction allows the geminal dialkylation of the carbonyl groups of aromatic aldehydes and ketones and the geminal aryl-alkylation of aliphatic analogues.