24015-63-2Relevant academic research and scientific papers
STEREOCHEMISTRY OF AMINE-CATALYZED KNOEVENAGEL REACTIONS
Tanikaga, Rikuhei,Konya, Naoto,Kaji, Aritsune
, p. 1583 - 1586 (2007/10/02)
The amine-catalyzed Knoevenagel reactions of aldehydes and active methylene compounds containing two activating groups were found to involve many reversible steps, and the diastereomeric intermediary condensation compounds yielded thermodynamically stable products via carbanionic intermediates stablized and sterically affected by two activating groups.
