24045-74-7

Upstream product

• 2881-83-6 ethyl 4-methoxybenzoylacetate 
• 100-06-1 1-(4-methoxyphenyl)ethanone 

Downstream Products

• 107151-73-5 4-(4-methoxy-phenyl)-2-(4-sulfamoyl-phenyl)-thiazole-5-carboxylic acid 
• 146368-58-3 ethyl 2-chloro-3-hydroxy-3-(4-methoxyphenyl)propanoate 
• 1242025-25-7 ethyl 2-acetoxy-3-(4-methoxyphenyl)-3-oxopropanoate 
• 1333320-92-5 ethyl 2-acetoxy-3-(4-methoxyphenyl)-3-(4-methoxyphenylamino)acrylate 
• 1333321-10-0 ethyl 2-acetoxy-3-(4-methoxyphenyl)-3-(4-methoxyphenylamino)propanoate 
• 33172-00-8 (+/-)-ethyl 3-hydroxy-3-(4-methoxyphenyl)propanoate 
• 4973-18-6 (+/-)-1-chloro-2-hydroxy-2-(p-methoxyphenyl)ethane 
• 102174-80-1 4-(4-methoxy-phenyl)-2-(4-sulfamoyl-phenyl)-thiazole-5-carboxylic acid ethyl ester 

Relevant academic research and scientific papers

Electrochemical chlorination and bromination of electron-deficient C[sbnd]H bonds in quinones, coumarins, quinoxalines and 1,3-diketones

The electrochemistry-promoted chlorination and bromination of electron-deficient C[sbnd]H bonds was developed, using quinones, coumarins, quinoxalines and 1,3-diketones. This protocol features readily available and safe halogen sources (hydrochloric acid and KBr), high site-selectivity and mild reaction conditions. It could provide an efficient access to a series of chlorinated and brominated quinones, coumarins, quinoxalines and 1,3-diketones.

Highly diastereoselective and enantioselective synthesis of α-hydroxy β-amino acid derivatives: Lewis base catalyzed hydrosilylation of α-acetoxy β-enamino esters

By design: A series of α-acetoxy-β-enamino esters 1 were synthesized and then subjected to catalytic asymmetric hydrosilylation. In the presence of a chiral Lewis base catalyst, the reactions proceeded smoothly to provide a wide range of chiral α-acetoxy β-amino acid derivatives in high yields with good diastereoselectivities and enantioselectivities. Copyright