24099-56-7

Upstream product

• 2272-45-9 benzal-p-toluidine 
• 31429-28-4 phenyl-p-tolylimino-acetonitrile 
• 106-49-0 p-toluidine 
• 134-81-6 benzil 
• 78604-82-7 α-p-toluidino-deoxybenzoin 
• 5722-91-8 1,2-diphenyl-2-(phenylamino)ethanone 
• 24099-52-3 (Z)-1,2-diphenyl-N,N'-di(p-methylphenyl)ethylene-1,2-diamine 

Downstream Products

• 71727-46-3 4,5-Diphenyl-1,3-di-p-tolyl-1,3-dihydro-imidazole-2-thione 
• 73376-02-0 phenyl-(phenylthio)-<(4-methylphenyl)-imino>-methane 
• 97531-35-6 2-Phenoxy-2-oxo-1,3-bis<4-methylphenyl>-4,5-diphenyl-2,3-dihydro-1H-P^V-1,3,2-diazaphosphole 
• 142160-41-6 (((C₆H₅)2C₂N₂(C₆H₄CH₃)2)Mn)2(C₄H₈O)2 
• 172219-72-6 bis(η(5)-pentamethylcyclopentadienyl)(1,4-bis(4-methylphenyl)-2,3-diphenyl-1,4-diazabuta-1,3-diene)yttrium 
• 202146-43-8 (N,N'-bis(4-tolyl)-1,2-diphenylethylenediimine)(eta.⁽⁶⁾-2-trimethylsilyl-4,5-dimethylphosphinine)Fe 
• 143732-81-4 1,4-bis(4-methylphenyl)-2,3-diphenyl-1,4-diaza-1,3-butadiene*ZrCl₄ 
• 115331-58-3 tetracarbonyl-{1,2-di-(4-methylanilino)stilbene}molybdenum⁽⁰⁾ 
• 115331-59-4 tetracarbonyl-{N,N'-dimethyl-1,2-di-(4-methylanilino)stilbene}molybdenum⁽⁰⁾ 
• 77014-47-2 1,3-bis-4,5-diphenyl-2-benzylimino-2,3-dihydroimidazole 
• 134-81-6 benzil 
• 77014-44-9 N,N'-dimethyl-p-toluidinostilbene 

Relevant academic research and scientific papers

Microwave-assisted efficient synthesis of diimines in dry media using silica gel supported sodium hydrogen sulfate as reusable solid support

A simple and efficient method for synthesis of diimines using silica gel supported sodium hydrogen sulfate as reusable solid support in solvent-free conditions under microwave irradiation is described.

A novel decyanogenative coupling of α-cyanoimines mediated by samarium. A facile route to α-diketimines

Conversion of α-cyanoimines 1 into α-diketimines 2 has been achieved successfully by using samarium diiodide in dry tetrahydrofuran in high yields without formation of anilinoanil 3, 1,2-diamines 4 or anilides 5.

Formation of benzil diimines by microwave-assisted reaction of benzil with aromatic amines on alumina surface without solvent

The microwave-assisted solvent-free reaction of benzil with aromatic amines (in 1 : 2 molar ratio) on an alumina surface for 4 min affords benzil diimines (1,2,3,4-tetraaryl-1,4-diaza-1,3-butadienes).

A novel reductive dimerization/oxidative dehydrogenation of aldimines mediated by lanthanoid metals

A lanthanoid metal-mediated novel reductive dimerization/oxidative dehydrogenation of a variety of aldimines has been achieved. Aromatic aldimines (1) were dimerized in the presence of 0.5 mol of ytterbium metal (Yb) and 1-naphthaldehyde (1-NpCHO) to give

Synthesis and characterization of 9,10-bis(arylimino)-9,10-dihydrophenanthrenes, the structure of (Z,Z)-9,10-bis(phenylimino)-9,10-dihydrophenanthrene and PdCl2-[(E,E)-9,10-bis(phenylimino)-9,10-dihydrophenanthrene] in the solid state and in so

The synthesis and characterization of substituted phenanthrene-9,10-quinone diimines of the type 9,10-bis(arylimino)-9,10-dihydrophenanthrene (aryl-BIP) is described. These rigid bisnitrogen ligands have been synthesized by a metal-mediated cyclodehydroge

and : New Types of Phenyl-Substituted 1,4-Diaza-1,3-diene Ligands

Two extreme situations in 1,4-diaza-1,3-diene (DAD) chemistry are described.Reaction of phenyl-substituted DAD 1a-c with lithium in the molecular ratio of 1:2 affords in high yield the extremely air-sensitive complexes (2a-c).The structure of 2b has been determined by X-ray diffraction.Each of the Li+ ions is coordinated by the two terminal N atoms of the s-cis-configurated DAD dianion and by two molecules of THF.Protonation of ZrCl4*DAD (3a) by HCl in THF gives the ionic complexes (4), which contains a protonated + cation.The structure of the sterically crowded N=C-C=N skeleton of the + cation is not influenced by the positive charge and adopts the unusual Z-gauche-Z conformation. Key Words: Lithium compounds / Enediamide structure / 1,4-Diaza-1,3-diene, protonated / Hydrogen bond

NOVEL AND CONVENIENT SYNTHESES OF SUBSTITUTED 1,4-DIAZOCINES AND 1,4-DIAZONINES

Treatment of dianils with sodium in dry ether followed by addition of 1,4-dichlorobutane and 1,5-dichloropentane gave 1,2,3,4-tetraaryl-1,4,5,6,7,8-hexahydro-1,4-diazocines and 1,2,3,4-tetraaryl-4,5,6,7,8,9-hexahydro-1H-1,4-diazonines respectively.