24110-24-5Relevant academic research and scientific papers
Straightforward synthesis of substituted p-Quinones: Isolation of a key intermediate and use as a bridging ligand in a diruthenium complex
Das, Hari Sankar,Weisser, Fritz,Schweinfurth, David,Su, Cheng-Yong,Bogani, Lapo,Fiedler, Jan,Sarkar, Biprajit
, p. 2977 - 2981 (2010)
(Figure Presented) Keep it simple: A new transamination method is reported for the synthesis of diamino-substituted p-quinones (see scheme). Asymmetrically substituted p-quinones are shown to be key intermediates in this reaction. The redox properties of these ligands are discussed and their utility in coordination and redox chemistry is shown with a representative example.
