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2H-Benzimidazole-2-thione,1,3-dihydro-1-(1-methylethyl)-(9CI), also known as tert-butyl 2-mercaptobenzimidazole, is an organic compound with the chemical formula C10H13N2S. It is a derivative of benzimidazole, a heterocyclic aromatic organic compound consisting of a benzene ring fused to an imidazole ring. The compound features a sulfur atom bonded to the benzene ring, forming a thiol group, and a tert-butyl group attached to the nitrogen atom. This chemical is primarily used as an antioxidant and a vulcanization accelerator in the rubber industry, as it helps to prevent the degradation of rubber and improve its overall performance. Due to its chemical structure, it exhibits excellent thermal stability and resistance to oxidation, making it a valuable additive in various industrial applications.

2416-65-1

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2416-65-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 2416-65-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,4,1 and 6 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 2416-65:
(6*2)+(5*4)+(4*1)+(3*6)+(2*6)+(1*5)=71
71 % 10 = 1
So 2416-65-1 is a valid CAS Registry Number.
InChI:InChI=1/C10H12N2S/c1-7(2)12-9-6-4-3-5-8(9)11-10(12)13/h3-7H,1-2H3,(H,11,13)

2416-65-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-propan-2-yl-1H-benzimidazole-2-thione

1.2 Other means of identification

Product number -
Other names 1-Isopropyl-1H-benzoimidazole-2-thiol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2416-65-1 SDS

2416-65-1Downstream Products

2416-65-1Relevant academic research and scientific papers

Synthesis and Structural Characterization of Tris(isopropylbenzimidazol-2-ylthio)methyl Zinc Complexes, [TitmPriBenz]ZnX: Modulation of Transannular Zn-C Interactions

Ruccolo, Serge,Rauch, Michael,Parkin, Gerard

, p. 1708 - 1718 (2018)

Tris(1-isopropylbenzimidazol-2-ylthio)methane ([TitmPriBenz]H) is obtained by treatment of 1-isopropyl-1,3-dihydro-2H-benzimidazole-2-thione with NaH followed by CHI3. The reaction of [TitmPriBenz]H with Me2Zn affords the zinc methyl complex [κ3-TitmPriBenz]ZnMe, which provides access to [TitmPriBenz]ZnOAr (Ar = p-C6H4Br), [κ3-TitmPriBenz]ZnH, {[TitmPriBenz]Zn}[HB(C6F5)3], {[TitmPriBenz]Zn}[MeB(C6F5)3], and {[TitmPriBenz]Zn}[BPh4]. X-ray diffraction demonstrates that the hydride and methyl complexes [κ3-TitmPriBenz]ZnH and [κ3-TitmPriBenz]ZnMe exhibit κ3 coordination of the [TitmPriBenz] ligand, whereas [TitmPriBenz]ZnOAr and {[TitmPriBenz]Zn}[HB(C6F5)3] exhibit κ4 coordination and adopt an atrane motif. The transannular Zn-C distances in [TitmPriBenz]ZnX (X = H, Me, OAr) and {[TitmPriBenz]Zn}+ span a range of 2.093(4)-2.367(2) ?, with the shortest corresponding to {[TitmPriBenz]Zn}+ and the longest corresponding to [TitmPriBenz]ZnOAr. The variation is attributed to the Zn-C bond in four-coordinate {[TitmPriBenz]Zn}+ being a two-center-two-electron interaction, whereas that in five-coordinate [TitmPriBenz]ZnOAr is a component of a three-center-four-electron interaction, in which the HOMO is approximately an spn hybrid lone pair orbital on carbon.

CRBN LIGANDS AND USES THEREOF

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Paragraph 00416; 00418, (2019/08/20)

The present invention provides compounds, compositions thereof, and methods of using the same for the inhibition of CRBN, and the treatment of CRBN-mediated disorders.

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