2416-98-0Relevant academic research and scientific papers
The catalytic intermolecular orthoarylation of phenols
Bedford, Robin B.,Coles, Simon J.,Hursthouse, Michael B.,Limmert, Michael E.
, p. 112 - 114 (2003)
The use of Wilkinson's catalyst with diisopropylphosphinite ligands acting as cocatalysts allows the catalytic orthoarylation of phenols [Eq. (1)], a process that relies on a C-H activation of a phenol that has been incorporated into the cocatalyst by transesterification.
P(NMe2)3-promoted ortho-selective arylation of phenols with diaryliodonium triflates via rhodium catalysis
Liu, Qi-Sheng,Wang, De-Yin,Yang, Jin-Fei,Ma, Zhong-Yi,Ye, Mengchun
supporting information, p. 3591 - 3595 (2017/06/13)
Rh-catalyzed ortho-selective arylation of free phenol with diaryliodonium triflates to widely existed phenol-containing biaryls have been developed. The use of P(NMe2)3, tBuOLi and CH3CN proved to be critical for the ortho-selectivity of this reaction.
Catalytic Intermolecular Ortho-Arylation of Phenols
Bedford, Robin B.,Limmert, Michael E.
, p. 8669 - 8682 (2007/10/03)
The use of rhodium catalysts such as [RhCl(PPh3)3] or [{RhCl(COD)}2] with PiPr2(OAr) or P(NMe 2)3 co-catalysts allows the ortho-selective intermolecular arylation of phenols. The reaction p
