241818-05-3Relevant articles and documents
A New Approach to Remote Asymmetric Induction in the Diastereoselective Reduction of γ-Keto Esters by Use of a Chiral Podand as Chiral Auxiliary
Tamai, Yasufumi,Koike, Shinji,Ogura, Atsuhiko,Miyano, Sotaro
, p. 799 - 800 (2007/10/02)
An efficient 1,7-asymmetric induction was achieved with up to 82percent diastereoisomeric excess (d.e.) in the diastereoselective reduction of the γ-keto ester 4 and o-acetylbenzoate 6 using a chiral podand 2 as a chiral auxiliary.