24263-54-5

Upstream product

• 109240-04-2 cyano-1 methyl-4 methylsulfinyl-1 cyclohexene-3 
• 920-37-6 2-Chloroacrylonitrile 
• 115010-71-4 (E)-2-(3-Methylbuta-1,3-dien-1-yl)benzo[1,3,2]dioxaborole 
• 78-79-5 isoprene 

Relevant academic research and scientific papers

1,3-Dienylboronates in Diels-Alder reaction: Part III

New examples of Diels-Alder reactions involving 1,3-disubstituted 1,3-dienylboronates are reported. Various dienophiles were tested. With methyl acrylate as the dienophile, lower reaction temperature, shorter reaction time and better stereocontrol have been reached with the use of a steochiometric amount of Lewis acid EtAlCl2.

DIENOPHILIE DES OLEFINES CAPTODATIVES: CYCLOADDITIONS DE DIELS-ALDER DE L'α-METHYLTHIO-ACRYLONITRILE ET TRANSFORMATION DES ADDUITS

The cycloaddition reactions of the α-methylthio-acrylonitrile with 1,3-dienes are investigated.The uncatalyzed thermal reactions proceed in high yields very stereoselectively with cyclic dienes and especially even room temperature with cyclopentadiene.In