24264-41-3Relevant academic research and scientific papers
Acid-mediated cyclotransformations of 4a-substituted 4H-4a,5- dihydroindeno[1,2-b]pyridines as a new route to 9a-substituted 1H-fluorenes
Stupnikova,Muceniece,Lusis
, p. 197 - 206 (2008/12/20)
4a-Substituted dihydroindenopyridines undergo cleavage of the C (9b)=N bond in water-containing acidic medium, resulting in the formation of diastereomeric ethyl α-acetyl-β-(2,3-dihydro-1,3-dioxo- 1H-inden-2-yl)-β-phenylpropionates and 9a-substituted 1,9a-dihydrofluore- none derivatives. The cyclization of α-acetyl-β-(2,3-dihydro-1,3- dioxo-1H-inden-2-yl)-β-phenyl-propionates with benzylammonium acetate affords 3-benzylamino-1,9a-dihydrofluorenones. The methanobenzo[a]azulene compound is also found among cyclization products.
