243117-78-4

Upstream product

• 14505-28-3 ethyl 2?cyano?3?p?tolylbut?2?enoate 
• 37610-80-3 1,3-dioxolan-2-ylethylmagnesium bromide 
• 20049-37-0 2-cyano-3-p-tolyl-cis-crotonic acid ethyl ester 

Downstream Products

• 518013-95-1 5-[1,3]dioxolan-2-yl-3-methyl-3-p-tolyl-pentanoic acid methyl ester 
• 518013-96-2 6-hydroxy-3-methyl-3-p-tolyl-hexanoic acid methyl ester 
• 518013-97-3 6-bromo-3-methyl-3-p-tolyl-hexanoic acid methyl ester 
• 705928-77-4 3-methyl-6-oxo-3-p-tolyl-hexanoic acid methyl ester 
• 111621-35-3 (+/-)-Tochuinyl acetate 
• 51941-57-2 (1R^*,2S^*)-1,2-Dimethyl-2-(4-methylphenyl)cyclopentanemethanol 

Relevant academic research and scientific papers

Stereoselective total syntheses of (±)-1,14-herbertenediol and (±)-tochuinyl acetate and facile total syntheses of (±)-α-herbertenol, (±)-β-herbertenol and (±)-1,4-cuparenediol

Stereoselective total syntheses of (±)-1,14-herbertenediol (7) and (±)-tochuinyl acetate (10) and facile total syntheses of (±)-α-herbertenol (2), (±)-β-herbertenol (3) and (±)-1,4-cuparenediol (8) have been successfully accomplished involving intramolecu

Facile total synthesis of (±)-α-herbertenol, (±)-α-cuparenone and (±)-HM-1 methyl ether involving alkylation of hindered esters

The total syntheses of (±)-α-herbertenol 1, (±)-α-cuparenone 4 and (±)-HM-1 methyl ether 3 have been successfully accomplished involving α,α- dimethylation of the esters 8a, 17 and 8b respectively as key steps.