24332-87-4

Upstream product

• 100-52-7 benzaldehyde 
• 24332-89-6 methyl-(α-D-lyxo-3-deoxy-hexopyranoside) 
• 2880-96-8 methyl 2,3-anhydro-4,6-dioxabenzylidene-α-D-talopyranose 
• 16697-40-8 methyl-[O⁴,O⁶-((S)-benzylidene)-S-methyl-3-thio-β-D-idopyranoside] 
• 15384-63-1 methyl 2,3-di-O-p-tolylsulfonyl-4,6-O-benzylidene-α-D-galactopyranoside 
• 2880-96-8 (1aR,2S,6R,7aR,7bR)-2-Methoxy-6-phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene 
• 86420-78-2 methyl 2,3-anhydro-4,6-O-benzylidene-β-D-talopyranoside 

Downstream Products

• 56405-85-7 methyl-[O⁴,O⁶-((S)-benzylidene)-O²-methyl-β-D-lyxo-3-deoxy-hexopyranoside] 
• 56405-85-7 methyl-[O⁴,O⁶-((S)-benzylidene)-O²-methyl-α-D-lyxo-3-deoxy-hexopyranoside] 

Relevant academic research and scientific papers

The formation of branched-chain deoxypentofuranosides by ring contraction in the reductive desulfonyloxylation of hexopyranoside p-toluenesulfonates

Several methyl 6-deoxy-, 6-deoxy-6-halo-, and 6-O-p-tolylsulfonylhexopyranoside 2- and 4-p-toluenesulfonates reacted readily with lithium triethylborohydride in boiling tetrahydrofuran under reductive desulfonyloxylation at C-2 and C-4, respectively, and