24341-84-2

Upstream product

• 873-51-8 phenylborondichloride 
• 3867-18-3 2-vinylaniline 
• 67114-34-5 2-chloro-1,2-dihydro-1,2-benzaborine 
• 100-58-3 phenylmagnesium bromide 
• 5339-85-5 2-aminophenethyl alcohol 
• 934-56-5 trimethyl(phenyl)stannane 
• 100123-15-7 chloro-phenoxy-phenyl-borane 
• 960-71-4 triphenylborane 
• 591-50-4 iodobenzene 
• 3262-89-3 triphenylboroxine 
• 71-43-2 benzene 
• 2622-55-1 bis(1,2-azabora-2-naphtyl)-oxide 

Downstream Products

• 1105696-59-0 tricarbonyl[(4a,5,6,7,8,8a-η)-1,2-dihydro-2-phenyl-1,2-benzaborine]chromium 
• 1105696-61-4 tricarbonyl[1,2-dihydro-2-(η6-phenyl)-1,2-benzaborine]chromium 
• 1616635-46-1 3-(N-Boc-indol-5-yl)-2-phenyl-2,1-borazaronaphthalene 
• 1616635-45-0 3-(3,5-dimethylisoxazol-4-yl)-2-phenyl-2,1-borazaronaphthalene 
• 1616635-44-9 3-(3-furanyl)-2-phenyl-2,1-borazaronaphthalene 
• 1616635-43-8 2-phenyl-3-(3-thienyl)-2,1-borazaronaphthalene 
• 1616635-42-7 3-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)-2-phenyl-2,1-borazaronaphthalene 
• 1616635-41-6 3-(3-nitrophenyl)-2-phenyl-2,1-borazaronaphthalene 
• 1616635-40-5 3-(4-fluorophenyl)-2-phenyl-2,1-borazaronaphthalene 
• 1616634-74-2 2,3-diphenyl-2,1-borazaronaphthalene 
• 1616634-99-1 3-bromo-2-phenyl-1,2-dihydrobenzo[e][1,2]azaborinine 

Relevant academic research and scientific papers

Rhodium-catalyzed boron arylation of 1,2-azaborines

A Sn-phony in B! BN isosteres of biphenyl compounds are prepared through Rh-catalyzed cross-coupling between 2-chloro-1,2-azaborines and arylstannanes (see scheme). The synthetic method should enable investigations of structure-activity relationships (SAR

Method for Accessing Nitrogen-Containing, B-Heteroaryl-Substituted 2,1-Borazaronaphthalenes

The azaborine motif provides a mimic of aromatic systems through replacement of a C=C bond with a B-N bond. In particular, 2,1-borazaronaphthalenes, accessible through robust methods of synthesis and subsequent functionalization, afford an ideal platform to use for a variety of applications. However, the scope of substructures for this archetype has been limited by the lack of nitrogen-containing heteroaryls that can be incorporated within them. In this study, modified reaction conditions were developed to provide access to a wider range of substructures.

Accessing Elaborated 2,1-Borazaronaphthalene Cores Using Photoredox/Nickel Dual-Catalytic Functionalization

A highly effective method for derivatizing 2,1-borazaronaphthalene cores using ammonium alkylbis(catecholato)silicates via photoredox/nickel dual catalysis is reported. By forging Csp3-Csp2 bonds via this approa

A convergent, modular approach to functionalized 2,1-borazaronaphthalenes from 2-aminostyrenes and potassium organotrifluoroborates

Azaborines are an important class of compounds with applications in both medicinal chemistry and materials science. The first borazaronaphthalene, 2-chloro-2,1-borazaronaphthalene, was reported in 1959; however, access to more highly functionalized substructures has been limited because of the harsh reaction conditions required to displace the chloride on boron. A convergent approach has been developed to synthesize disubstituted 2,1-borazaronaphthalenes from N-substituted 2-aminostyrenes and potassium organotrifluoroborates, where the potassium organotrifluoroborate is converted to the active R-BX2 species (X = Cl or F) in situ by addition of a fluorophile. Starting from aryl-, heteroaryl-, alkynyl-, alkenyl-, and alkyltrifluoroborates, a library of highly functionalized 2,1-borazaronaphthalenes were synthesized in one step under mild, transition-metal-free conditions.

Tricarbonylchrommm complexes of 1,2-Dihydro-1,2-benzazaborines

l,2-Dihydro-2-phenyl-1,2-benzazaborine reacts with Cr(CO) 3(CH3CN)3 in THF at 140 °C to form complex 18, in which the phenyl is >n6-bound to chromium. 1,2-Dihydro-2-methyl-1,2-benzazaborine reacts with Cr(CO)su