3867-18-3

Basic information

• Product Name: 2-AMINOSTYRENE
• Synonyms: 2-AMINOSTYRENE;2-Styrenamine;o-Vinylaniline;2-vinylbenzenamine;2-ethenylaniline
• CAS NO: 3867-18-3
• Molecular Formula: C₈H₉N
• Molecular Weight: 119.16376
• Mol File: 3867-18-3.mol
• Article Data: 81

Chemical Properties

• Boiling Point: 212.46°C (rough estimate)
• Flash Point: 93.84 °C
• Appearance: /
• Density: 1.0181
• Refractive Index: 1.6124
• Storage Temp.: 2-8°C(protect from light)
• PKA: 3.86±0.10(Predicted)
• CAS DataBase Reference: 2-AMINOSTYRENE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-AMINOSTYRENE(3867-18-3)
• EPA Substance Registry System: 2-AMINOSTYRENE(3867-18-3)

Safety Data

• Hazardous Substances Data: 3867-18-3(Hazardous Substances Data)

Usage

Uses

2-Vinylaniline is a useful chemical for preparation of cyclopeptides solomonamides, a possible antitumor agent.

Upstream product

• 5339-85-5 2-aminophenethyl alcohol 
• 98-82-8 Isopropylbenzene 
• 102968-90-1 2-ethylthio-N-allylaniline 
• 579-71-5 2-nitrostyrene 
• 52670-38-9 2-ethynylaniline 
• 615-36-1 2-bromoaniline 
• 15016-42-9 2-vinylbenzeneboronic acid 
• 62-53-3 aniline 
• 5344-90-1 2-Aminobenzyl alcohol 
• 1031-15-8 methyltriphenylphosphonium chloride 
• 116509-93-4 2-p-Tolyl-2λ⁴-benzo[c][1,2]thiazine 2-oxide 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 552-89-6 2-nitro-benzaldehyde 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 24341-84-2 2-phenyl-1,2-dihydrobenzo[e][1,2]azaborinine 
• 29124-68-3 N-(2-vinylphenyl)acetamide 
• 860738-57-4 N,N'-bis-(2-vinyl-phenyl)-adipamide 
• 143879-49-6 2,2,2-trifluoro-N-(2-vinylphenyl)acetamide 
• 76466-73-4 ethyl 2-chloro-2-<(o-vinylphenyl)azo>acetoacetate 
• 1504-06-9 3-methylindolin-2-one 
• 553-03-7 3,4-dihydro-2(1H)-quinolone 
• 894810-88-9 N-(2-vinylphenyl)methanesulphonamide 
• 360059-87-6 2-(N-nitrobenzenesulfonyl)aminostyrene 
• 875897-55-5 (E)-1-phenyl-N-(2-vinylphenyl)methanimine 
• 1007873-41-7 C₂₉H₃₇N₃O₂ 
• 1196959-07-5 C₂₅H₁₉NO₂ 
• 1211481-19-4 2-(3,3-dideuterioallyl)-N-(2-vinylphenyl)aniline 
• 93-19-6 2-isobutylquinoline 

Relevant articles and documents

BN Polystyrenes: Emerging Optical Materials and Versatile Intermediates

BN polystyrenes are an emerging class of polyolefins functionalized with aromatic side chains in which at least one CC bond is replaced with a BN bond. This class of structures exhibits unusual photophysical properties relative to organic polymers. BN pol

Synthesis of triphenylarsonium [11C]methylide, a new 11C-precursor. Application in the preparation of [2-11C]indole

The synthesis of the new and highly reactive 11C-precursor triphenylarsonium [11C]methylide 1 and its conversion into [2-11C]indole 6 is described. [11C]Methyltriphenylarsonium iodide 4 was prepared by quaterniz

METHOD OF REDUCING AROMATIC NITRO COMPOUNDS

A method for reducing a substrate selected from 2-methyl-5-nitropyridine and methyl 4-(2-fluoro-3-nitrobenzyl)piperazine-1-carboxylate is provided catalysed by a nitroreductase and a disproportionation agent.

Directing-group-assisted markovnikov-selective hydrothiolation of styrenes with thiols by photoredox/cobalt catalysis

In contrast with the well-developed radical thiol-ene reaction to access anti-Markovnikov-type products, the research on the catalytic Markovnikov-selective hydrothiolation of alkenes is very restricted. Because of the catalyst poisoning of metal catalysts by organosulfur compounds, limited examples of transition-metal-catalyzed thiol-ene reactions have been reported. However, in this work, a directing-group-assisted hydrothiolation of styrenes with thiols by photoredox/cobalt catalysis is found to proceed smoothly to afford Markovnikov-type sulfides with excellent regioselectivity.

Uncovering New Excited State Photochemical Reactivity by Altering the Course of the de Mayo Reaction

An unprecedented and previously unknown photochemical reactivity of 1,3-dicarbonyl compounds is observed with amino-alkenes leading to dihydropyrans. This novel photochemical reactivity changes the established paradigm related to the De Mayo reaction between 1,3-dicarbonyl compounds and alkenes. This new reaction allows convenient access to the Marmycin core in a single step from commercially available reactants. The origin and scope of this new photoreaction is detailed with preliminary photophysical and mechanistic investigations.