243462-39-7

Basic information

• Product Name: N-(2-methoxybenzyl)prop-2-en-1-amine
• Synonyms: benzenemethanamine, 2-methoxy-N-2-propen-1-yl-
• CAS NO: 243462-39-7
• Molecular Formula: C₁₁H₁₅NO
• Molecular Weight: 177.2429
• Mol File: 243462-39-7.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 254.5°C at 760 mmHg
• Flash Point: 102.6°C
• Density: 0.967g/cm³
• Vapor Pressure: 0.0172mmHg at 25°C
• Refractive Index: 1.513
• CAS DataBase Reference: N-(2-methoxybenzyl)prop-2-en-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-methoxybenzyl)prop-2-en-1-amine(243462-39-7)
• EPA Substance Registry System: N-(2-methoxybenzyl)prop-2-en-1-amine(243462-39-7)

Safety Data

• Hazardous Substances Data: 243462-39-7(Hazardous Substances Data)

Upstream product

• 42551-56-4 N-o-Methoxybenzylidenallylamin 
• 135-02-4 ortho-anisaldehyde 
• 107-11-9 1-amino-2-propene 

Downstream Products

• 1382449-34-4 C₁₈H₂₃NO₄ 
• 243462-41-1 N-allyl-2,2,2-trifluoro-N-(2-methoxy-benzyl)-acetamide 

Relevant articles and documents

Rhodium-Catalyzed Regiodivergent Hydrothiolation of Allyl Amines and Imines

The regiodivergent Rh-catalyzed hydrothiolation of allyl amines and imines is presented. Bidentate phosphine ligands with larger natural bite angles (βn ≥ 99°), for example, DPEphos, dpph, or L1, promote a Markovnikov-selective hydrothiolation in up to 88% yield and >20:1 regioselectivity. Conversely, when smaller bite angle ligands (βn ≤ 86°), for example, dppbz or dppp, are employed, the anti-Markovnikov product is formed in up to 74% yield and >20:1 regioselectivity. Initial mechanistic investigations are performed and are consistent with an oxidative addition/olefin insertion/reductive elimination mechanism for each regioisomeric pathway. We hypothesize that the change in regioselectivity is an effect of diverging coordination spheres to favor either Rh-S or Rh-H insertion to form the branched or linear isomer, respectively.

Photo-induced intramolecular arene-olefin meta-cycloaddition of 5-phenyl-fluorinated-pent-1-enes

A series of fluorinated angular and linear triquinanes and their aza-analogues have been synthesized by photo-induced intramolecular meta-cycloaddition of 5-phenyl-fluorinated-pent-1-enes.