244124-41-2

Upstream product

• 124-38-9 carbon dioxide 

Downstream Products

• 1426250-63-6 4-tert-butyl-5-{4-[N-(4-ethoxycarbonylbutyl)benzimidazol-2-yl]-3-methoxyphenyl}-3,3-dimethyl-2,3-dihydrofuran 
• 1426250-60-3 4-tert-butyl-5-[3-hydroxy-4-(N-methylbenzimidazol-2-yl)phenyl]-3,3-dimethyl-2,3-dihydrofuran 
• 1426250-61-4 4-tert-butyl-5-[3-hydroxy-4-(N-phenylbenzimidazol-2-yl)phenyl]-3,3-dimethyl-2,3-dihydrofuran 
• 1426250-62-5 4-tert-butyl-5-{4-[N-(4-carboxybutyl)benzimidazol-2-yl]-3-hydroxyphenyl}-3,3-dimethyl-2,3-dihydrofuran 
• 1426250-66-9 5-tert-butyl-1-[3-hydroxy-4-(N-phenylbenzimidazol-2-yl)phenyl]-4,4-dimethyl-2,6,7-trioxabicyclo[3.2.0]heptane 
• 1426250-68-1 2,2,4,4-tetramethyl-3-oxopentyl 4-(benzimidazol-2-yl)-3-hydroxybenzoate 
• 1426250-69-2 2,2,4,4-tetramethyl-3-oxopentyl 3-hydroxy-4-(N-methylbenzimidazol-2-yl)benzoate 
• 1426250-70-5 2,2,4,4-tetramethyl-3-oxopentyl 3-hydroxy-4-(N-phenylbenzimidazol-2-yl)benzoate 
• 1426250-71-6 2,2,4,4-tetramethyl-3-oxopentyl 4-[N-(4-carbonylbutyl)benimidazol-2-yl]-3-hydroxybenzoate 
• 1426250-59-0 5-[4-(benzimidazol-2-yl)-4-tert-butyl-3-hydroxyphenyl]-3,3-dimethyl-2,3-dihydrofuran 
• 1426250-56-7 5-[4-(benzimidazol-2-yl)-3-methoxyphenyl]-4-tert-butyl-3,3-dimethyl-2,3-dihydrofuran 
• 1426250-57-8 4-tert-butyl-5-[3-methoxy-4-(N-methylbenzimidazol-2-yl)phenyl]-3,3-dimethyl-2,3-dihydrofuran 
• 1426250-58-9 4-tert-butyl-5-[3-methoxy-4-(N-phenylbenzimidazol-2-yl)phenyl]-3,3-dimethyl-2,3-dihydrofuran 

Relevant academic research and scientific papers

Synthesis of bicyclic dioxetanes bearing a 4-(benzimidazol-2-yl)-3- hydroxyphenyl group and their base-induced chemiluminescent decomposition in an aprotic medium and in an aqueous medium

Bicyclic dioxetane, 5-tert-butyl-4,4-dimethyl-2,6,7-trioxabicyclo[3.2.0] heptane, bearing a 4-(benzimidazol-2-yl)-3-hydroxyphenyl group at the 1-position and its N-substituted benzimidazolyl-analogs were synthesized. N-Methylbenzimidazolyl-analog and N-phenylbenzimidazolyl-analog were found to undergo charge-transfer-induced decomposition(CTID) to effectively give light in both TBAF/MeCN and in NaOH/H2O. The CTID of N-(4-carboxybutyl) benzimidazolyl-analog gave also effectively light both in MeCN and in H2O. On the other hand, chemiluminescent CTID of the unsubstituted benzimidazolyl-analog changed depending on the base used: TBAF/MeCN induced weak emission of yellow light due to a dianion of the dioxetane, while TMG(tetramethylguanidine)/MeCN induced strong emission of blue light due to a monoanion of the dioxetane.