244187-82-4Relevant academic research and scientific papers
Ruthenium-based NHC-arene systems as ring-opening metathesis polymerisation catalysts
Ledoux, Nele,Allaert, Bart,Verpoort, Francis
, p. 5578 - 5583 (2007)
The availability of starting materials, the complexity of the preparative routes and the cost to make the catalyst are key in the development of industrially relevant olefin metathesis catalysts. With this in mind, new synthetic routes, which lead to alte
A simple synthesis of [RuCl2(NHC)(p-cymene)] complexes and their use in olefin oxidation catalysis
Ma, Xinyuan,Guillet, Sébastien G.,Peng, Min,Van Hecke, Kristof,Nolan, Steven P.
, p. 3959 - 3965 (2021/03/29)
A simple and efficient synthetic route to [RuCl2(NHC)(p-cymene)] and [Ru(CO3)(NHC)(p-cymene)] complexes making use of a weak base, under aerobic conditions, is reported. This method enables access to a series of NHC-ruthenium compounds with moderate to good yields under mild conditions. The Ru pre-catalysts were successfully used in olefin oxidation catalysis at low catalyst loading and reach complete conversion in short times.
Synthesis and catalytic evaluation of ruthenium-arene complexes generated using imidazol(in)ium-2-carboxylates and dithiocarboxylates
Delaude, Lionel,Sauvage, Xavier,Demonceau, Albert,Wouters, Johan
, p. 4056 - 4064 (2009/12/05)
The ability of five imidazol(in)ium-2-carboxylates and dithiocarboxylates bearing cyclohexyl, mesityl, or 2,6-diisopropylphenyl substituents on their nitrogen atoms to act as NHC precursors for in situ catalytic applications was probed in ruthenium-promot
