244260-50-2Relevant academic research and scientific papers
Direct observation of reversible C(sp3)-H bond activation. Characterization of the structures of both Ir complexes before and after C-H bond activation by using a flexible P-N heterochelate hybrid ligand
Kataoka, Yasutaka,Imanishi, Masahiro,Yamagata, Tsuneaki,Tani, Kazuhide
, p. 3563 - 3565 (1999)
Direct observation of reversible C-H bond activation of a C(sp3)-H bond is shown for the Ir(I) complex 2a, which has a coordinatively flexible heterochelate hybrid PNn=1 ligand (1a). Full characterization data for the Ir(I) and Ir(III) complexes, including their X-ray structures and estimation of the thermodynamic and kinetic parameters for the C-H bond activation, are provided.
