244260-82-0

Basic information

• Product Name: 2-(4-methoxybenzyloxy)hex-5-enoic acid
• Synonyms: 2-(4-methoxybenzyloxy)hex-5-enoic acid
• CAS NO: 244260-82-0
• Molecular Weight: 250.295
• Mol File: 244260-82-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-(4-methoxybenzyloxy)hex-5-enoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-methoxybenzyloxy)hex-5-enoic acid(244260-82-0)
• EPA Substance Registry System: 2-(4-methoxybenzyloxy)hex-5-enoic acid(244260-82-0)

Safety Data

• Hazardous Substances Data: 244260-82-0(Hazardous Substances Data)

Upstream product

• 201539-47-1 ethyl 2-hydroxyhex-5-enoate 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 

Downstream Products

• 244260-83-1 (2RS,1'S,2'E) 2-(4-methoxybenzyloxy)hex-5-enoic acid 4'-(tert-butyl(diphenyl)silyloxy)-1'-methylbut-2'-enyl ester 
• 795308-11-1 (2R/S,1'S)-1'-{[(tert-butyldiphenylsilyl)oxy]methyl}-6'-(1,3-dioxolan-2-yl)-4'-methyl-2',4'-hexadien-1'-yl 2-[(4-methoxybenzyl)oxy]-5-hexenoate 
• 173934-26-4 (R)-(-)-homocitric acid lactone 
• 442913-68-0 (E)-(3aS,4S,7S,11aR)-7-(4-Methoxy-benzyloxy)-2,2-dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one 
• 851626-50-1 2-(4-Methoxy-benzyloxy)-6-trimethylsilanyl-hex-5-ynoic acid (E)-(S)-4-(tert-butyl-diphenyl-silanyloxy)-1-methyl-but-2-enyl ester 
• 851626-47-6 (2RS,1'S,2'E) 2-(4-methoxybenzyloxy)hex-5-ynoic acid 4'-(tert-butyl(diphenyl)silyloxy)-1'-methylbut-2'-enyl ester 
• 851626-37-4 2-(4-methoxybenzyloxy)hex-5-ynoic acid methyl ester 
• 851626-23-8 2-(4-methoxybenzyloxy)hex-5-ynoic acid 
• 851626-35-2 2-(4-methoxy-benzyloxy)-5-oxo-pentanoic acid methyl ester 
• 851626-45-4 (2RS,1'S,2'E) 2-(4-methoxybenzyloxy)hex-5-enoic acid 4'-(tert-butyl(diphenyl)silyloxy)-1',3'-dimethylbut-2'-enyl ester 
• 851626-46-5 (2RS,1'S,2'Z) 2-(4-methoxybenzyloxy)hex-5-enoic acid 4'-(tert-butyl(diphenyl)silyloxy)-1',3'-dimethylbut-2'-enyl ester 

Relevant articles and documents

Enantioselective synthesis of isotopically labeled homocitric acid lactone

A concise synthesis of homocitric acid lactone was developed to accommodate systematic placement of carbon isotopes (specifically 13C) for detailed studies of this cofactor. This new route uses a chiral allylic alcohol, available in multigram quantities from enzymatic resolution, as a starting material, which transposes asymmetry through an Ireland-Claisen rearrangement.

Total syntheses of the phytotoxic lactones herbarumin I and II and a synthesis-based solution of the pinolidoxin puzzle

A concise approach to a family of potent herbicidal 10-membered lactones is described on the basis of ring-closing metathesis (RCM) as the key step for the formation of the medium-sized ring. This includes the first total syntheses of herbarumin I (1) and