244282-19-7

Basic information

• Product Name: phenyl 3,4,6-tri-O-benzyl-2-O-(2-propenyl)-1-thio-α-D-mannopyranoside
• Synonyms: phenyl 3,4,6-tri-O-benzyl-2-O-(2-propenyl)-1-thio-α-D-mannopyranoside
• CAS NO: 244282-19-7
• Molecular Weight: 582.761
• Mol File: 244282-19-7.mol

Chemical Properties

• CAS DataBase Reference: phenyl 3,4,6-tri-O-benzyl-2-O-(2-propenyl)-1-thio-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 3,4,6-tri-O-benzyl-2-O-(2-propenyl)-1-thio-α-D-mannopyranoside(244282-19-7)
• EPA Substance Registry System: phenyl 3,4,6-tri-O-benzyl-2-O-(2-propenyl)-1-thio-α-D-mannopyranoside(244282-19-7)

Safety Data

• Hazardous Substances Data: 244282-19-7(Hazardous Substances Data)

Upstream product

• 138181-67-6 phenyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 

Downstream Products

• 244282-24-4 cyclohexyl 3,4,6-tri-O-benzyl-β-D-mannopyranoside 
• 90465-39-7 benzyl 3,4,6-tri-O-benzyl-β-D-mannopyranoside 
• 244282-21-1 (2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-5-(1-benzyloxy-2-iodo-1-methyl-ethoxy)-2-benzyloxymethyl-6-phenylsulfanyl-tetrahydro-pyran 
• 244282-22-2 (3aR,5R,5aS,8aS,8bR)-5-[1-((2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-iodo-1-methyl-ethoxymethyl]-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran 
• 244282-20-0 (2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-5-(2-iodo-1-methoxy-1-methyl-ethoxy)-6-phenylsulfanyl-tetrahydro-pyran 
• 112330-11-7 (3,4,6-tri-O-benzyI-β-D-mannopyranosyl)-(1→6)-1,2,3,4-di-O-isoprpopylidene-α-D-galactopyranoside 
• 244282-23-3 (2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-5-(1-cyclohexyloxy-2-iodo-1-methyl-ethoxy)-6-phenylsulfanyl-tetrahydro-pyran 

Relevant articles and documents

N-Iodosuccinimide-mediated intramolecular aglycon delivery

Enol ethers may be accessed via Tebbe methylenation of either 2-O acetates or para-methoxybenzoates. N-Iodosuccinimide may then be employed to achieve both tethering and thioglycoside activation allowing the stereoselective synthesis of α-glucosides and β-mannosides, either in a one or two step procedure.