244286-78-0Relevant academic research and scientific papers
DISAL glycosyl donors for the synthesis of a linear hexasaccharide under mild conditions.
Petersen, Lars,Laursen, Jane B,Larsen, Kim,Motawia, M Saddik,Jensen, Knud J
, p. 1309 - 1312 (2003)
[reaction: see text] The new class of glycosyl donors with a methyl 3,5-dinitrosalicylate (DISAL) anomeric leaving group has proved efficient for glycosylation under strictly neutral, mildly basic, or mildly acidic conditions. Here, we report the synthesi
Direct synthesis of pseudo-disaccharides by rearrangement of unsaturated disaccharides
Pearce, Alan James,Sollogoub, Matthieu,Mallet, Jean-Maurice,Sinay, Pierre
, p. 2103 - 2117 (2007/10/03)
The series of unsaturated disaccharides 10-14 undergo stereoselective reductive rearrangement with TIBAL (triisobutylaluminium) to afford (1→4) and (1→6) ether-linked pseudo-disaccharides 2-9.
