244286-77-9

Upstream product

• 5346-81-6 phenyl 2,3,6-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-1-thio-β-D-glucopyranoside 
• 27891-73-2 phenylthio 2,3,4,6-terta hydroxy-α-D-glucopyranosyl-(1→4)-2,3,6-triylhydroxy-β-D-glucopyranoside 
• 3616-19-1 1,2,3,6,2',3',4',6'-octa-O-acetylmaltose 
• 108-98-5 thiophenol 
• 309913-14-2 Phenyl 2,3,6-tri-O-acetyl-4-O-(2,3-di-O-acetyl-4,6-O-benzylidene-α-D-glycopyranosyl)-1-thio-β-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 87470-75-5 phenyl 4-O-(4,6-O-benzylidene-α-D-glucopyranosyl)-1-thio-β-D-glucopyranoside 

Downstream Products

• 244286-71-3 methyl 2,3,6-tri-O-benzyl-4-O-(2,3,4-tri-O-benzyl-6-deoxy-α-D-xylo-hex-5-enopyranosyl)-α-D-glucopyranoside 
• 244286-79-1 methyl 2,3,6,2',3',4'-hexa-O-benzyl-α-D-maltoside 
• 244286-80-4 methyl 2,3,6,2',3',4'-hexa-O-benzyl-6'-deoxy-6'-iodo-α-D-maltoside 
• 244286-73-5 phenyl 2,3,6-tri-O-benzyl-4-O-(2,3,4-tri-O-benzyl-6-deoxy-α-D-xylohex-5-enopyranosyl)-1-thio-β-D-glucopyranoside 
• 250335-04-7 Phenyl 2,3,6-tri-O-benzyl-4-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-1-thio-β-D-glucopyranoside 
• 244286-78-0 phenyl 2,3,6,2',3',4'-hexa-O-benzyl-1-thio-β-D-maltoside 

Relevant academic research and scientific papers

New phenyl 6,4'-substituted-1-thio-β-maltosides, building blocks for the synthesis of linear and branched malto-oligosaccharides

An efficient strategy to synthesize a number of new phenylthio-maltoside derivatives in yields from 55 to 95% is described. These derivatives can be used as suitable building blocks for stepwise synthesis of starch derived malto-oligosaccharides.

Direct synthesis of pseudo-disaccharides by rearrangement of unsaturated disaccharides

The series of unsaturated disaccharides 10-14 undergo stereoselective reductive rearrangement with TIBAL (triisobutylaluminium) to afford (1→4) and (1→6) ether-linked pseudo-disaccharides 2-9.