24451-23-8

Upstream product

• 779-02-2 9-methylanthracene 
• 98-88-4 benzoyl chloride 

Downstream Products

• 24451-25-0 (10-methylanthracen-9-yl)benzyl chloride 
• 292041-10-2 (2a,8-dibenzoyl-3-methyl-2b,8b-dihydro-2aH-cyclopropa[3,4]pentaleno[1,2-b]naphthalen-8c-yl)-phenyl-methanone 
• 292041-03-3 9-benzoyl-10-methylnaphthobarrelene 
• 24451-24-9 (10-methylanthracen-9-yl)benzyl alcohol 

Relevant academic research and scientific papers

Photobase generator

The object of the present invention is to provide a photobase generator capable of efficiently generating amines (tertiary amines and amidine) high in catalytic activity by sensing light with a wavelength of from 350 to 500 nm (especially, from 400 to 500 nm). The present invention is a photobase generator characterized in being represented by general formula (1) or (2). Y+ is a quaternary ammonio group of general formula (3) to (5), and X? is a counter anion selected from among a borate anion, a phenolate anion, and a carboxylate anion.

Reactions of Copper(II) Halides with Aromatic Compounds. Part XII. Reactions of 9-Methyl-10-phenylanthracene, 1,4,9-Trimethylanthracene, 9,10-Dimethylanthracene and 1,5-Dichloro-9-methylanthracene in Methanol.

The title compounds react with copper(II) bromide in methanol to give the corresponding 9-methoxymethyl compounds. 1,4,9-Trimethylanthracene and 1,5-dichloro-9-methylanthracene also gave 1,2-di-(1,4-dimethyl-9-anthryl)ethane (6) and 1,5-dichloro-9,10-dimethoxy-9,10-dihydroanthracene (9) respectively.The formation of all these products can be interpreted in terms of initial electron transfer oxidation of the substituted anthracene to its radical cation, which either subsequently loses a proton to give the substituted 9-anthrylmethyl radical or undergoes solvent capture.