24456-98-2Relevant academic research and scientific papers
COMPOSITION OF PRODUCTS AND MECHANISM OF THE REACTION OF OZONE WITH 2,6-DI(tert-BUTYL)-4-METHYLPHENOL
Razumovskii, S. D.,Konstantinova, M. L.,Zaikov, G. E.
, p. 949 - 952 (1992)
It was shown that two series of products with opening and with preservation of the aromatic nucleus are formed in the reaction of ozone with ionol, and a mechanism was proposed for the reaction. Keywords: ozone, phenols, 2,6-di(tert-butyl)-4-methylphenol.
Inverse electron demand hetero-Diels-Alder reaction in preparing 1,4-benzodioxin from o-quinone and enamine
Zhang, Jinsong,Taylor, Chris,Bowman, Erich,Savage-Low, Leo,Lodewyk, Michael W.,Hanne, Larry,Wu, Guang
supporting information, p. 6298 - 6302 (2013/11/06)
A process for synthesizing 1,4-benzodioxin, through oxidation of a phenol to an o-quinone followed by treatment with an enamine, has been developed. Adduct stereochemistry is found to be retained via this one-pot reaction. The method uses hypervalent iodine reagent under mild conditions and is compatible with a wide scope of phenols and enamines.
