24459-12-9Relevant academic research and scientific papers
Arene-promoted lithiation of 1,n-dihaloalkanes (n=2-6): a comparative study
Abou, Abdeslam,Foubelo, Francisco,Yus, Miguel
, p. 10417 - 10424 (2007/10/03)
The reaction of 1,n-dichloroalkanes 3a (n=2-6) with an excess of lithium powder and a catalytic amount of 4,4′-di-tert-butylbiphenyl (DTBB; 2.5 mol %) in the presence of different carbonyl compounds [ButCHO, PhCHO, Et2CO, (CH2/
TiCl4/Mg/BrCH2CH2Br Reagent System: A 1,2-Diorganometallic Equivalent
Rao, S. Achyutha,Periasamy, M.
, p. 1583 - 1586 (2007/10/02)
1,2-Diorganometallic species generated utilizing the TiCl4/Mg/BrCH2CH2/Br reagent system reacts with ketones to give the corresponding 1,4-diols and/or 1,2-diols in moderate yields.
