244607-41-8Relevant academic research and scientific papers
Gold-catalyzed intermolecular addition of carbonyl compounds to 1,6-enynes: Reactivity, scope, and mechanistic aspects
Schelwies, Mathias,Moser, Ralph,Dempwolff, Adrian L.,Rominger, Frank,Heimchen, Guenter
, p. 10888 - 10900 (2009)
A full account of a recently discovered gold(I)-catalyzed reaction, a cycloaddition of carbonyl compounds to enynes yielding 2-oxabicyclo[3.1.0] hexanes with four stereogenic centers, is presented. The reaction proceeds with very high diastereoselectivity
