244623-33-4

Upstream product

• 36616-60-1 (1R,4R,6R)-4-isopropenyl-1-methyl-7-oxabicyclo[4.1.0]heptan-2-one 
• 97643-04-4 2,2-dimethyl-3(R)-hydroxy-5(R)-isopropylenecyclohexanone 
• 244623-31-2 (3R,5S,6R)-3-Allyl-5-isopropenyl-2,2,6-trimethyl-3-trimethylsilanyloxy-cyclohexanone 
• 244623-23-2 (1S,3R,5R)-1-Benzyl-5-isopropenyl-2,2-dimethyl-cyclohexane-1,3-diol 
• 244623-30-1 (3R,5S)-3-Allyl-5-isopropenyl-2,2-dimethyl-3-trimethylsilanyloxy-cyclohexanone 
• 244623-36-7 (1R,3R,5R)-1-Allyl-5-isopropenyl-2,2-dimethyl-cyclohexane-1,3-diol 
• 244623-29-8 (3R,5S)-3-Allyl-3-hydroxy-5-isopropenyl-2,2-dimethyl-cyclohexanone 
• 6485-40-1 (R)-Carvone 
• 244623-32-3 (3S,5S,6R)-5-Isopropenyl-2,2,6-trimethyl-3-(2-oxo-propyl)-3-trimethylsilanyloxy-cyclohexanone 

Downstream Products

• 244623-34-5 (S)-1-Allyl-5-(2-hydroxy-2-methyl-pent-4-enyl)-2,6,6-trimethyl-5-trimethylsilanyloxy-cyclohex-2-enol 

Relevant academic research and scientific papers

A new carvone based construction of the ring-A of taxoids

A synthesis of the fully functionalized A-ring of taxoids from the commercially available monoterpenic chiron R-carvone is outlined. In this approach, regio- and stereoselective restructuring of alkyl substituents and functionalities is effected on the periphery while retaining the six membered core of carvone.