97643-04-4

Upstream product

• 677326-54-4 2,3-epoxy-5-isopropenyl-2-methylcyclohexanone 
• 74-88-4 methyl iodide 
• 6485-40-1 (R)-Carvone 
• 97643-05-5 (3R,5R)-3-hydroxy-2-methyl-5-(1-methylethenyl)cyclohexanone 
• 36616-60-1 (1R,4R,6R)-4-isopropenyl-1-methyl-7-oxabicyclo[4.1.0]heptan-2-one 

Downstream Products

• 244623-23-2 (1S,3R,5R)-1-Benzyl-5-isopropenyl-2,2-dimethyl-cyclohexane-1,3-diol 
• 721921-05-7 (1R,3R,5R)-5-isopropenyl-1,2,2-trimethylcyclohexane-1,3-diol 
• 868553-66-6 (3R,5R)-3-hydroxy-5-isopropyl-2,2-dimethylcyclohexan-1-one 
• 913093-74-0 (1R,3R,5R)-5-isopropenyl-2,2-dimethyl-1-vinylcyclohexane-1,3-diol 
• 913093-76-2 (3S,5S)-3-hydroxy-5-isopropenyl-2,2-dimethyl-3-[(2R)-oxiran-2-yl]cyclohexanone 
• 913093-82-0 (2S,4S,5S)-4-hydroxymethyl-6,6,8-trimethyl-2-phenyl-1,3-dioxaspiro[4.5]dec-8-en-7-one 
• 913093-77-3 (3S,5S)-3-hydroxy-3-[(1S)-1-hydroxy-2-(phenylsulfanyl)ethyl]-5-isopropenyl-2,2-dimethylcyclohexanone 
• 913093-81-9 (2S,4S,5S,8R,9S)-4-hydroxymethyl-9-isopropenyl-6,6,8-trimethyl-2-phenyl-1,3-dioxaspiro[4.5]decan-7-one 
• 913093-73-9 {(2S,4S,5S,9S)-7-allyl-9-hydroxy-6,6,8-trimethyl-2-phenyl-1,3-dioxaspiro[4.5]dec-7-en-4-yl}methyl acetate 
• 913093-85-3 {(2S,4S,5S,9R)-7-allyl-9-hydroxy-6,6,8-trimethyl-2-phenyl-1,3-dioxaspiro[4.5]dec-7-en-4-yl}methyl acetate 
• 913093-78-4 (2S,4S,5S,9S)-9-isopropenyl-6,6-dimethyl-2-phenyl-4-[(phenylthio)methyl]-1,3-dioxaspiro[4.5]decan-7-one 
• 913093-79-5 (2S,4S,5S,8R,9S)-9-isopropenyl-6,6,8-trimethyl-2-phenyl-4-[(phenylthio)methyl]-1,3-dioxaspiro[4.5]decan-7-one 
• 913093-80-8 (2S,4S,5S,8R,9S)-9-isopropenyl-6,6,8-trimethyl-2-phenyl-4-[(phenylsulfinyl)methyl]-1,3-dioxaspiro[4.5]decan-7-one 
• 913093-84-2 {(2S,4S,5S,9S)-9-[tert-butyl(dimethyl)silyloxy]-6,6,8-trimethyl-7-(2-oxoethyl)-2-phenyl-1,3-dioxaspiro[4.5]dec-7-en-4-yl}methyl acetate 

Relevant academic research and scientific papers

Short new route to the chiral spiro-tetrahydrofuran subunit common to some terpenoids

Synthetic strategy based on a stereoselective iodoetherification reaction of a carvone-derived hydroxyalkene unit has been developed for the asymmetric synthesis of the key spiro-tetrahydrofuran subunit common to some naturally occurring terpenoids. Copyright Taylor & Francis, Inc.

A new carvone based construction of the ring-A of taxoids

A synthesis of the fully functionalized A-ring of taxoids from the commercially available monoterpenic chiron R-carvone is outlined. In this approach, regio- and stereoselective restructuring of alkyl substituents and functionalities is effected on the periphery while retaining the six membered core of carvone.

Lithium naphthalenide induced reductive cleavage of α,β-epoxy ketones: An efficient procedure for the preparation of β-hydroxy ketones

Lithium naphthalenide presents itself as a mild and efficient reagent for the cleavage of α,β-epoxy ketones to give the corresponding β-hydroxy ketones in good yields.

Stereochemistry of the Reductive Alkylation of α,β-Epoxy Ketones

α-Epoxy ketones have been found to be useful intermediates for regiospecific alkylation of ketones.We have examined the steric course of the alkylation and shown it to be highly stereoselective.