245111-04-0

Basic information

• Product Name: ClCo(C₆H₈NOHNO)2((C₆H₅)3P)
• CAS NO: 245111-04-0
• Molecular Weight: 639.036
• Mol File: 245111-04-0.mol

Chemical Properties

• CAS DataBase Reference: ClCo(C₆H₈NOHNO)2((C₆H₅)3P)(CAS DataBase Reference)
• NIST Chemistry Reference: ClCo(C₆H₈NOHNO)2((C₆H₅)3P)(245111-04-0)
• EPA Substance Registry System: ClCo(C₆H₈NOHNO)2((C₆H₅)3P)(245111-04-0)

Safety Data

• Hazardous Substances Data: 245111-04-0(Hazardous Substances Data)

Upstream product

• 492-99-9 1,2-cyclohexanedionedioxime 
• 603-35-0 triphenylphosphine 

Downstream Products

• 70106-19-3 N₃Co(C₆H₈NOHNO)2((C₆H₅)3P) 

Relevant articles and documents

Synthesis, characterization and cis-trans influence in cobaloximes with nioxime

A synthetic scheme leading to the (X)(Y)bis(1,2-cyclohexanedionedioximato)cobalt(III) complexes, where X = Cl, N3, ClCH2, CH3, C2H5 and Y = PPh3 and Py is reported. The complexes have been characterized by the usual spectroscopic techniques and have been compared with the reported analogous compounds having other dioximes as the equatorial ligands. The first crystal structure of an inorganic cobaloxime with 1,2-cyclohexanedionedioxime (Nioxime) is reported. For a range of X ligands, a clear trend between 31P, 13C, 1H chemical shifts of the equatorial and axial ligands as well as with the Co → chgH charge transfer band has been observed.