24528-76-5Relevant academic research and scientific papers
Cp and indenyl ruthenium complexes containing dithione derivatives: Synthesis, antibacterial and antifungal study
Dkhar, Lincoln,Joshi, Santa Ram,Ka-Ot, Agustine Lamin,Kaminsky, Werner,Kollipara, Mohan Rao,Sawkmie, Merrily
, (2020)
A series of cationic complexes [(Cp/Ind)Ru(к2(SS)-L)(PPh3)]PF6 (1–6) are obtained by the reaction of [CpRu(PPh3)2Cl] or [(Ind)Ru(PPh3)2Cl] (Cp = η5-C5H5, Ind = η5-C9H7) with respective dithione derivatives 1,2-di(piperidin-1-yl)ethane-1,2-dithione (L1), 1,2-dimorpholinoethane-1,2-dithione (L2) and 1,2-dithiomorpholinoethane-1,2-dithione (L3). All the compounds are characterized using spectroscopic techniques. The molecular structures of complexes 1, 2 and 4 are established by single-crystal X-ray diffraction studies. Antimicrobial studies were tested against three strains of bacterial microorganisms Staphylococcus aureus (gram + ve), Bacillus subtilis (gram + ve), Klebsiella pneumoniae (gram -ve) and one strain of fungal microorganism Candida albicans.
Synthesis of N,N'-Disubstituted Dithiooxamide Derivatives by the Modified Willgerodt–Kindler Reaction
Boyarskii, V. P.,Eliseenkov, E. V.,Petrov, A. A.,Ponomareva, T. N.
, p. 781 - 787 (2020/07/03)
Abstract: The conditions of the reaction of trichloroethylene with sulfur and amines were optimized (the modified Willgerodt–Kindler reaction). The reaction of tetrachloroethylene with sulfur and some basic primary and secondary amines of the aliphatic series in DMF under mild conditions leads to N,N'-disubstituted dithiooxamides in 30–70% yields and with a 100% conversion of tetrachloroethylene.
