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Tetrachloroethylene
Cas No: 127-18-4
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
CHemwill -- Tetrachloroethylene
Cas No: 127-18-4
USD $ 1.0-1.0 / Metric Ton 1 Metric Ton 5 Metric Ton/Day Chemwill Asia Co., Ltd. Contact Supplier
Tetrachloroethylene (1Mg/ML in Methanol) [for Water Analysis]
Cas No: 127-18-4
No Data 1 Gram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
Tetrachloroethylene
Cas No: 127-18-4
USD $ 2.0-3.0 / Kilogram 1 Kilogram 100 Metric Ton/Week EAST CHEMSOURCES LIMITED Contact Supplier
Factory Supply Perchloroethylene
Cas No: 127-18-4
No Data 1 1 Ality Chemical Corporation Contact Supplier
1,1,2,2-tetrachloroethene
Cas No: 127-18-4
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Perchlorethylene
Cas No: 127-18-4
USD $ 1.0-1.0 / Kilogram 1 Kilogram 1000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
tetrachloroethylene
Cas No: 127-18-4
USD $ 1.0-3.0 / Metric Ton 1 Metric Ton 10 Metric Ton/Day Hebei yanxi chemical co.,LTD. Contact Supplier
127-18-4
Cas No: 127-18-4
USD $ 1.0-1.0 / Kilogram 1 Kilogram 100000 Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier
BLOOM TECH Advanced API/Technology support Tetrachloroethylene CAS 127-18-4
Cas No: 127-18-4
No Data 1 Gram 3 Metric Ton/Month Shaanxi BLOOM TECH Co.,Ltd Contact Supplier

127-18-4 Usage

127-18-4 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (32437)  Tetrachloroethylene, Ultrapure, Spectrophotometric Grade, 99+%    127-18-4 1L 926.0CNY Detail
Alfa Aesar (32437)  Tetrachloroethylene, Ultrapure, Spectrophotometric Grade, 99+%    127-18-4 4L 2732.0CNY Detail
Alfa Aesar (32437)  Tetrachloroethylene, Ultrapure, Spectrophotometric Grade, 99+%    127-18-4 *4x1L 3288.0CNY Detail
Alfa Aesar (B20089)  Tetrachloroethylene, 99%    127-18-4 100ml 142.0CNY Detail
Alfa Aesar (B20089)  Tetrachloroethylene, 99%    127-18-4 500ml 310.0CNY Detail
Alfa Aesar (B20089)  Tetrachloroethylene, 99%    127-18-4 2500ml 456.0CNY Detail
Supelco (48609)  Tetrachloroethylenesolution  certified reference material, 200 μg/mL in methanol 127-18-4 000000000000048609 207.09CNY Detail
Supelco (40083)  Tetrachloroethylenesolution  certified reference material, 5000 μg/mL in methanol 127-18-4 000000000000040083 400.14CNY Detail
Sigma-Aldrich (15889)  DensityStandard1623kg/m3  H&D Fitzgerald Ltd. Quality 127-18-4 15889-10ML-F 2,341.17CNY Detail

127-18-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name tetrachloroethene

1.2 Other means of identification

Product number -
Other names TETRACHLORO ETHYLENE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:127-18-4 SDS

127-18-4Synthetic route

N-(2,2,2-trichloroethylidene)benzenesulfonamide
55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

complex of sulfur dioxide with dimethylamine
21326-49-8

complex of sulfur dioxide with dimethylamine

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

chloroform
67-66-3

chloroform

C

N,N-dimethyl-N′-(phenylsulfonyl)formimidamide
13707-43-2

N,N-dimethyl-N′-(phenylsulfonyl)formimidamide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 24h;A n/a
B n/a
C 98%
N-(2,2,2-trichloroethylidene)benzenesulfonamide
55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

diethylamine
109-89-7

diethylamine

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

chloroform
67-66-3

chloroform

C

N1,N1-diethyl-N2-phenylsulfonylformamidine
29665-24-5

N1,N1-diethyl-N2-phenylsulfonylformamidine

Conditions
ConditionsYield
In dichloromethane at 0℃; for 24h;A n/a
B n/a
C 98%
hexachloroethane
67-72-1

hexachloroethane

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
In tetrachloromethane at 300℃; for 0.000555556h; Temperature; Flow reactor; Pyrolysis;97%
at 600℃;
With pyrographite at 700℃;
Hexachlorobutadiene
87-68-3

Hexachlorobutadiene

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
With aluminum (III) chloride; chlorine at 280 - 750℃; Temperature;95%
N-(2,2,2-trichloroethylidene)benzenesulfonamide
55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

dimethyl amine
124-40-3

dimethyl amine

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

chloroform
67-66-3

chloroform

C

N,N-dimethyl-N′-(phenylsulfonyl)formimidamide
13707-43-2

N,N-dimethyl-N′-(phenylsulfonyl)formimidamide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 24h;A n/a
B n/a
C 92%
N-(2,2,2-trichloroethylidene)benzenesulfonamide
55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

complex of sulfur dioxide with dimethylamine
21326-49-8

complex of sulfur dioxide with dimethylamine

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

chloroform
67-66-3

chloroform

C

N-Phenylsulfonyl-N,N'-dimethylformamidine hydrochloride

N-Phenylsulfonyl-N,N'-dimethylformamidine hydrochloride

Conditions
ConditionsYield
In Trichloroethylene at 20℃; for 24h;A n/a
B n/a
C 89%
octachloro-cyclobutane
7294-43-1

octachloro-cyclobutane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

Hexachlorobutadiene
87-68-3

Hexachlorobutadiene

C

hexachlorocyclobutene
6130-82-1

hexachlorocyclobutene

Conditions
ConditionsYield
at 506℃; Product distribution;A 0.3%
B 86%
C 1.2%
tetrachloromethane
56-23-5

tetrachloromethane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

methane
34557-54-5

methane

C

chloroform
67-66-3

chloroform

D

carbon monoxide
201230-82-2

carbon monoxide

Conditions
ConditionsYield
With iron(II,III) oxide; sodium chloride at 25℃; pH=8.9; Kinetics;A 0.01%
B 1%
C 5.2%
D 82%
With hydroxysulfate green rust In water at 20℃; for 575h; pH=7.6; Product distribution;
pentachloroethane
76-01-7

pentachloroethane

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
With methyl diethylphosphinate at 150℃; for 10h;75%
With chlorine at 379.84℃; Gas phase; chemoselective reaction;33.8%
With nickel dichloride at 330℃;
1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

Trichloroethylene
79-01-6

Trichloroethylene

Conditions
ConditionsYield
With hydrogenchloride; oxygen at 379.84℃; for 18h;A 20.8%
B 64.3%
With CuCl2/KCl/attapulgite; chlorine at 379.84℃; Gas phase; chemoselective reaction;A 16.6%
B 45%
1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

Trichloroethylene
79-01-6

Trichloroethylene

C

pentachloroethane
76-01-7

pentachloroethane

Conditions
ConditionsYield
With hydrogenchloride; oxygen at 379.84℃;A 20.8%
B 64.3%
C 6.1%
N,N-Dichlorobenzenesulfonamide
473-29-0

N,N-Dichlorobenzenesulfonamide

1,2-Dichloroethylene
540-59-0

1,2-Dichloroethylene

A

benzenesulfonamide
98-10-2

benzenesulfonamide

B

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

C

Trichloroethylene
79-01-6

Trichloroethylene

D

N-(2,2,2-trichloroethylidene)benzenesulfonamide
55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

E

N-(2,2-dichloroethylidene)benzenesulfonamide
113791-97-2

N-(2,2-dichloroethylidene)benzenesulfonamide

F

N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide
79054-58-3

N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide

Conditions
ConditionsYield
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator;A n/a
B n/a
C n/a
D n/a
E n/a
F 54.1%
N,N-Dichlorobenzenesulfonamide
473-29-0

N,N-Dichlorobenzenesulfonamide

1,2-Dichloroethylene
540-59-0

1,2-Dichloroethylene

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

Trichloroethylene
79-01-6

Trichloroethylene

C

N-(2,2,2-trichloroethylidene)benzenesulfonamide
55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

D

N-(2,2-dichloroethylidene)benzenesulfonamide
113791-97-2

N-(2,2-dichloroethylidene)benzenesulfonamide

E

N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide
79054-58-3

N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide

F

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator;A n/a
B n/a
C n/a
D n/a
E 54.1%
F n/a
hexachloroethane
67-72-1

hexachloroethane

Ce(3+)*3C4H14NSi2(1-)*2C4H8O

Ce(3+)*3C4H14NSi2(1-)*2C4H8O

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

tetramethyldisilazane

tetramethyldisilazane

Conditions
ConditionsYield
In toluene for 18h; Reagent/catalyst; Solvent; Time; Inert atmosphere;A n/a
B 45%
1,2-Dichloroethylene
540-59-0

1,2-Dichloroethylene

N,N-dichloro-4-chlorobenzenesulfonamide
17260-65-0

N,N-dichloro-4-chlorobenzenesulfonamide

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

4-Chlorobenzenesulfonamide
98-64-6

4-Chlorobenzenesulfonamide

C

N-(2,2,2-trichloroethylidene)-4-chlorobenzenesulfonamide
81924-15-4

N-(2,2,2-trichloroethylidene)-4-chlorobenzenesulfonamide

D

N-(2,2-dichloroethylidene)-p-chlorobenzenesulfonamide
113791-98-3

N-(2,2-dichloroethylidene)-p-chlorobenzenesulfonamide

E

N-<2,2-dichloro-1-(N-p-chlorobenzenesulfonamido)ethyl>-p-chlorobenzenesulfonamide
113792-01-1

N-<2,2-dichloro-1-(N-p-chlorobenzenesulfonamido)ethyl>-p-chlorobenzenesulfonamide

F

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator;A n/a
B n/a
C n/a
D n/a
E 40.4%
F n/a
(2,2-dichloro-vinyl)-trimethyl-silane
18163-67-2

(2,2-dichloro-vinyl)-trimethyl-silane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

Trichloroethylene
79-01-6

Trichloroethylene

C

Trimethyl-(1,2,2,2-tetrachloro-ethyl)-silane

Trimethyl-(1,2,2,2-tetrachloro-ethyl)-silane

D

Chloromethyl-dimethyl-(1,2,2,2-tetrachloro-ethyl)-silane

Chloromethyl-dimethyl-(1,2,2,2-tetrachloro-ethyl)-silane

Conditions
ConditionsYield
With chlorine for 3h; Further byproducts given;A 1%
B 5%
C 30%
D 33%
With chlorine for 3h; Further byproducts given;A 1%
B 7%
C 30%
D 33%
Trichloroethylene
79-01-6

Trichloroethylene

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

pentachloroethane
76-01-7

pentachloroethane

Conditions
ConditionsYield
With chlorine at 379.84℃; Reagent/catalyst; Temperature;A 8.1%
B 11.2%
tetrachloromethane
56-23-5

tetrachloromethane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

hexachloroethane
67-72-1

hexachloroethane

Conditions
ConditionsYield
at 580℃; for 0.00433333h; Rate constant; Mechanism; several condition investigated;A 10.18%
B 2.51%
at 394.5 - 445.3℃; under 83.3 - 161.6 Torr; Kinetics; Equilibrium constant; Thermodynamic data; eq. const. at 696.6 K; ΔH at 298 K;
at 600 - 1500℃;
pentacarbonyl(methoxyphenylmethylene)tungsten(0)
37823-96-4

pentacarbonyl(methoxyphenylmethylene)tungsten(0)

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

methylene chloride
74-87-3

methylene chloride

C

dichloromethane
75-09-2

dichloromethane

D

chloroform
67-66-3

chloroform

Conditions
ConditionsYield
In tetrachloromethane byproducts: HCl, Cl2; further products; N2; stirred; gas-chromy., MAS; elem. anal.;A 6.8%
B 2%
C 0.2%
D 3.6%
piperidine
110-89-4

piperidine

tetrachloromethane
56-23-5

tetrachloromethane

pentachloroethane
76-01-7

pentachloroethane

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
at 20℃;
tetrachloromethane
56-23-5

tetrachloromethane

Isobutane
75-28-5

Isobutane

hexachloroethane
67-72-1

hexachloroethane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

tertiary butyl chloride
507-20-0

tertiary butyl chloride

Conditions
ConditionsYield
at 140℃;
tetrachloromethane
56-23-5

tetrachloromethane

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
Beim Durchleiten durch ein rotgluehendes Rohr;
at 1300 - 1400℃;
With hydrogen
tetrachloromethane
56-23-5

tetrachloromethane

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

hexachlorobenzene
118-74-1

hexachlorobenzene

Conditions
ConditionsYield
at 700℃;
propene
187737-37-7

propene

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
With tetrachloromethane; chlorine at 800℃;
diethyl ether
60-29-7

diethyl ether

hexachloroethane
67-72-1

hexachloroethane

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

1,1,1,2-tetrachoroethane
630-20-6

1,1,1,2-tetrachoroethane

C

pentachloroethane
76-01-7

pentachloroethane

D

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

diethyl ether
60-29-7

diethyl ether

hexachloroethane
67-72-1

hexachloroethane

sodium ethanolate
141-52-6

sodium ethanolate

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
at 140℃;
diethyl ether
60-29-7

diethyl ether

hexachloroethane
67-72-1

hexachloroethane

phenylmagnesium bromide

phenylmagnesium bromide

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

1,1,1,2-tetrachoroethane
630-20-6

1,1,1,2-tetrachoroethane

C

pentachloroethane
76-01-7

pentachloroethane

D

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

1,1-dichloroethane
75-34-3

1,1-dichloroethane

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Conditions
ConditionsYield
With chlorine; pyrographite at 450℃;
pentachloropropionyl chloride
812-25-9

pentachloropropionyl chloride

A

1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

B

hexachloroethane
67-72-1

hexachloroethane

Conditions
ConditionsYield
With aluminium trichloride at 60℃;
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

hypofluorous acid trifluoromethyl ester
373-91-1

hypofluorous acid trifluoromethyl ester

1,1,2,2-tetrachloro-1-fluoro-2-trifluoromethoxyethane
136649-69-9

1,1,2,2-tetrachloro-1-fluoro-2-trifluoromethoxyethane

Conditions
ConditionsYield
at 40.6℃;99.5%
at 160 - 195℃; under 750.075 Torr; for 31h;84.3%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

5-methyl-1H-2-benzothiopyran-1-one
681141-90-2

5-methyl-1H-2-benzothiopyran-1-one

2aα,8bα-1,1,2,2-tetrachloro-2,2a-dihydro-8-methyl-1H-cyclobuta[c][2]benzothiopyran-4-one

2aα,8bα-1,1,2,2-tetrachloro-2,2a-dihydro-8-methyl-1H-cyclobuta[c][2]benzothiopyran-4-one

Conditions
ConditionsYield
In acetonitrile for 12h; Irradiation;97%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Pd(CN(2,6-(2,6-(i-Pr)2C6H3)2C6H3))2
1182649-23-5

Pd(CN(2,6-(2,6-(i-Pr)2C6H3)2C6H3))2

Pd(η2-C2Cl4)(CN(2,6-(2,6-(i-Pr)2C6H3)2C6H3))2

Pd(η2-C2Cl4)(CN(2,6-(2,6-(i-Pr)2C6H3)2C6H3))2

Conditions
ConditionsYield
In toluene; pentane for 0.25h; Inert atmosphere; Schlenk technique; Glovebox;97%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

A

1,1,1-trifluoro-2,2-dichloroethane
306-83-2

1,1,1-trifluoro-2,2-dichloroethane

B

1,1,2-trichloro-2,2-difluoroethane
354-21-2

1,1,2-trichloro-2,2-difluoroethane

C

freon-121
354-14-3

freon-121

D

1,1,1,2-tetrafluoro-2-chloroethane
2837-89-0

1,1,1,2-tetrafluoro-2-chloroethane

Conditions
ConditionsYield
With hydrogen fluoride; antimony(III) fluoride; antimony pentafluoride at 125 - 139℃; under 16351.6 - 18376.8 Torr; for 3.7h;A 92.4%
B 0.9%
C 0.01%
D 0.4%
With hydrogen fluoride; antimony(III) fluoride; antimony pentafluoride at 122 - 140℃; under 17926.8 - 20252 Torr; for 3.6h;A 89.8%
B 0.3%
C 0.08%
D 3.1%
With hydrogen fluoride; antimony(III) fluoride; antimony pentafluoride at 124 - 140℃; under 18001.8 - 19201.9 Torr; for 3.1h;A 87.2%
B 1.1%
C 0.01%
D 0.5%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

copper hydroxide
20427-59-2

copper hydroxide

Trimethylenediamine
109-76-2

Trimethylenediamine

Cu2(C10H16N4Cl4)(H2O)4(4+)*4Cl(1-)*8H2O = [Cu2(C10H16N4Cl4)(H2O)4]Cl4*8H2O

Cu2(C10H16N4Cl4)(H2O)4(4+)*4Cl(1-)*8H2O = [Cu2(C10H16N4Cl4)(H2O)4]Cl4*8H2O

Conditions
ConditionsYield
In water; butan-1-ol refluxing in butanol (10 h), extraction (water); pptn. from aq. phase (concn., cooling); elem. anal.;92%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

(E)-tert-butyldimethyl[3-(tributylstannyl)prop-2-enyloxy]silane
90838-72-5, 110410-38-3, 134435-95-3, 86633-16-1, 81925-28-2, 86646-19-7

(E)-tert-butyldimethyl[3-(tributylstannyl)prop-2-enyloxy]silane

(6E,10E)-8,9-Bis((E)-3-((tert-butyldimethylsilyl)oxy)prop-1-en-1-yl)-2,2,3,3,14,14,15,15-octamethyl-4,13-dioxa-3,14-disilahexadeca-6,8,10-triene
1638292-74-6

(6E,10E)-8,9-Bis((E)-3-((tert-butyldimethylsilyl)oxy)prop-1-en-1-yl)-2,2,3,3,14,14,15,15-octamethyl-4,13-dioxa-3,14-disilahexadeca-6,8,10-triene

Conditions
ConditionsYield
With palladium diacetate; XPhos at 60℃; Stille Cross Coupling; Inert atmosphere;90%
With palladium diacetate; XPhos at 60℃; Stille Cross Coupling; Inert atmosphere;90%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

tributyl[(E)-2-trimethylsilylethenyl]stannane
58207-97-9

tributyl[(E)-2-trimethylsilylethenyl]stannane

((1E,5E)-3,4-bis((E)-2-(trimethylsilyl)vinyl)hexa-1,3,5-triene-1,6-diyl)bis(trimethylsilane)
1638178-58-1

((1E,5E)-3,4-bis((E)-2-(trimethylsilyl)vinyl)hexa-1,3,5-triene-1,6-diyl)bis(trimethylsilane)

Conditions
ConditionsYield
With palladium diacetate; XPhos at 60℃; Stille Cross Coupling; Inert atmosphere;89%
With palladium diacetate; XPhos at 60℃; Stille Cross Coupling; Inert atmosphere;89%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

sodium isopropanethiolate
20607-43-6

sodium isopropanethiolate

tetrakis-isopropylsulfanyl-ethene
39137-72-9

tetrakis-isopropylsulfanyl-ethene

Conditions
ConditionsYield
In N,N,N,N,N,N-hexamethylphosphoric triamide for 1h; Ambient temperature;85%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

hypofluorous acid trifluoromethyl ester
373-91-1

hypofluorous acid trifluoromethyl ester

A

CFC-112a
76-12-0

CFC-112a

B

dichloro-fluoro-acetyl chloride
354-17-6

dichloro-fluoro-acetyl chloride

C

1,1,2,2-tetrachloro-1-fluoro-2-trifluoromethoxyethane
136649-69-9

1,1,2,2-tetrachloro-1-fluoro-2-trifluoromethoxyethane

D

Trichloroacetyl chloride
76-02-8

Trichloroacetyl chloride

E

Dichloro-trifluoromethoxy-acetyl chloride

Dichloro-trifluoromethoxy-acetyl chloride

F

COCl2

COCl2

Conditions
ConditionsYield
With oxygen at 40.9℃; under 420.8 Torr; for 1.97833h; Product distribution; Mechanism; Rate constant; var. of partial pressure, temp.;A n/a
B n/a
C n/a
D 85%
E n/a
F n/a
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

fac-tricarbonyl(bis(diphenylphosphino)ethane)(η1-methyldithiobenzoate)tungsten
118050-71-8, 118050-81-0

fac-tricarbonyl(bis(diphenylphosphino)ethane)(η1-methyldithiobenzoate)tungsten

mer-tricarbonyl(bis(diphenylphosphino)ethane)(η2-methyldithiobenzoate)tungsten * tetrachloroethene

mer-tricarbonyl(bis(diphenylphosphino)ethane)(η2-methyldithiobenzoate)tungsten * tetrachloroethene

Conditions
ConditionsYield
In tetrahydrofuran isomerization in THF within about 48 h;; concn.; pptn. with tetrachloroethene; elem. anal.;;85%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

tetrabutyl-ammonium chloride
1112-67-0

tetrabutyl-ammonium chloride

C2Cl12Si4(2-)*2C16H36N(1+)

C2Cl12Si4(2-)*2C16H36N(1+)

Conditions
ConditionsYield
With hexachlorodisilane In dichloromethane at -10 - 20℃; for 12h; Inert atmosphere;85%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

Octanethiol
111-88-6

Octanethiol

A

Octyl-<1.2.2-trichlor-vinyl>-sulfid
36061-42-4

Octyl-<1.2.2-trichlor-vinyl>-sulfid

B

1-((E)-1,2-Dichloro-2-octylsulfanyl-vinylsulfanyl)-octane
130920-00-2

1-((E)-1,2-Dichloro-2-octylsulfanyl-vinylsulfanyl)-octane

Conditions
ConditionsYield
With potassium hydroxide In ethanol; N,N-dimethyl-formamide at 60 - 70℃;A n/a
B 83%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

diamantane-3-spiro-3'-diazirine
105522-49-4

diamantane-3-spiro-3'-diazirine

3-chlorodiamantane
30651-01-5

3-chlorodiamantane

Conditions
ConditionsYield
Irradiation;83%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

A

1,1,1-trifluoro-2,2-dichloroethane
306-83-2

1,1,1-trifluoro-2,2-dichloroethane

B

1,1,2-trichloro-2,2-difluoroethane
354-21-2

1,1,2-trichloro-2,2-difluoroethane

C

1,1,1,2-tetrafluoro-2-chloroethane
2837-89-0

1,1,1,2-tetrafluoro-2-chloroethane

Conditions
ConditionsYield
With hydrogen fluoride; antimony(III) fluoride; antimony pentafluoride at 129 - 143℃; under 17626.8 - 19502 Torr; for 4.1h;A 80.5%
B 0.3%
C 5.1%
With hydrogen fluoride; antimony pentafluoride at 135 - 143℃; under 18751.9 Torr; for 2.7h;A 26%
B 0.6%
C 25.8%
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