245736-29-2

Upstream product

• 67-56-1 methanol 
• 245736-27-0 (S)-1-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-4-{(4S,6R)-6-[(R)-1-(4-methoxy-benzyloxy)-pent-4-enyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-2-methyl-butane-1,3-dione 
• 2746-25-0 p-Methoxybenzyl bromide 
• 245736-20-3 (R)-2-(4-Methoxy-benzyloxy)-hex-5-en-1-ol 
• 245736-18-9 (R)-1-(trityloxy)hex-5-en-2-ol 
• 245736-25-8 {(4S,6R)-6-[(R)-1-(4-Methoxy-benzyloxy)-pent-4-enyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetaldehyde 
• 245736-23-6 (3S,5R,6R)-3,5-Dihydroxy-6-(4-methoxy-benzyloxy)-dec-9-enoic acid methyl ester 
• 245736-24-7 {(4S,6R)-6-[(R)-1-(4-Methoxy-benzyloxy)-pent-4-enyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-acetic acid methyl ester 
• 245736-19-0 1-Methoxy-4-((R)-1-trityloxymethyl-pent-4-enyloxymethyl)-benzene 

Downstream Products

• 245736-34-9 (S)-2-{(2S,6R)-2-Methoxy-6-[(R)-1-(4-methoxy-benzyloxy)-4-oxo-butyl]-4-[1-methoxycarbonyl-meth-(E)-ylidene]-tetrahydro-pyran-2-yl}-propionic acid benzyl ester 
• 245736-33-8 (S)-2-{(2S,6R)-2-Methoxy-6-[(R)-1-(4-methoxy-benzyloxy)-pent-4-enyl]-4-[1-methoxycarbonyl-meth-(E)-ylidene]-tetrahydro-pyran-2-yl}-propionic acid benzyl ester 
• 245736-35-0 C₃₃H₅₂O₉Si 
• 245736-31-6 [(2S,6R)-2-[(S)-2-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-1-methyl-2-oxo-ethyl]-2-methoxy-6-[(R)-1-(4-methoxy-benzyloxy)-pent-4-enyl]-tetrahydro-pyran-(4E)-ylidene]-acetic acid methyl ester 
• 245736-74-7 C₄₄H₆₁NO₁₂ 
• 245736-65-6 C₄₅H₆₃NO₁₂ 
• 245736-75-8 [21-amino-13-hydroxy-5-methoxy-10-(4-methoxy-benzyloxy)-4,14,18,27-tetramethyl-25-(2-methyl-propenyl)-3,15,19-trioxo-2,24,28-trioxa-tricyclo[21.3.1.1^5,9]octacos-20-en-7-ylidene]-acetic acid methyl ester 
• 245736-77-0 C₄₄H₆₂O₁₃ 
• 245736-58-7 (S)-2-{(2S,6R)-6-[(1R,4R,5R,7S,9R)-7-((S)-4-Benzyl-2-oxo-oxazolidine-3-carbonyl)-4-hydroxy-1-(4-methoxy-benzyloxy)-5,9-dimethyl-6-oxo-undec-10-ynyl]-2-methoxy-4-[1-methoxycarbonyl-meth-(E)-ylidene]-tetrahydro-pyran-2-yl}-propionic acid benzyl ester 
• 245736-71-4 C₅₃H₇₅NO₁₃Si 
• 245736-59-8 2-{6-[7-(4-benzyl-2-oxo-oxazolidine-3-carbonyl)-4-(tert-butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-5,9-dimethyl-6-oxo-undec-10-ynyl]-2-methoxy-4-methoxycarbonylmethylene-tetrahydro-pyran-2-yl}-propionic acid benzyl ester 

Relevant academic research and scientific papers

Synthesis and absolute stereochemical assignment of (+)-miyakolide

The first total synthesis of the marine macrolide miyakolide has been achieved, and its absolute stereochemistry has been determined. The carbon skeleton is assembled in a convergent fashion from three fragments via esterification, [3 + 2] dipolar cycload