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ETHYLENE GLYCOL METHACRYLATE PHOSPHATE, also known as EGMAP, is a phosphorus-containing monomer that is widely used in the production of flame-retardant materials, thermosetting resins, and has potential applications in biomedical materials and drug delivery systems due to its biocompatibility and ability to form hydrogels.

24599-21-1

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24599-21-1 Usage

Uses

Used in Flame-Retardant Materials:
ETHYLENE GLYCOL METHACRYLATE PHOSPHATE is used as a flame-retardant additive for improving the fire resistance of polymers, coatings, adhesives, and other materials.
Used in Thermosetting Resins:
ETHYLENE GLYCOL METHACRYLATE PHOSPHATE is used as a vinyl monomer for enhancing the mechanical and thermal properties of thermosetting resins in various applications.
Used in Biomedical Materials:
ETHYLENE GLYCOL METHACRYLATE PHOSPHATE is used as a component in the development of biocompatible materials for medical applications, such as implants and scaffolds, due to its ability to form hydrogels.
Used in Drug Delivery Systems:
ETHYLENE GLYCOL METHACRYLATE PHOSPHATE is used as a material for designing drug delivery systems, taking advantage of its biocompatibility and hydrogel-forming properties to control the release of therapeutic agents.

Check Digit Verification of cas no

The CAS Registry Mumber 24599-21-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,4,5,9 and 9 respectively; the second part has 2 digits, 2 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 24599-21:
(7*2)+(6*4)+(5*5)+(4*9)+(3*9)+(2*2)+(1*1)=131
131 % 10 = 1
So 24599-21-1 is a valid CAS Registry Number.
InChI:InChI=1/C6H10O3.H3O4P/c1-5(2)6(8)9-4-3-7;1-5(2,3)4/h7H,1,3-4H2,2H3;(H3,1,2,3,4)

24599-21-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name ETHYLENE GLYCOL METHACRYLATE PHOSPHATE

1.2 Other means of identification

Product number -
Other names 2-(methacryoyloxy)ethyl phosphate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:24599-21-1 SDS

24599-21-1Downstream Products

24599-21-1Relevant academic research and scientific papers

Complex coacervation of Mg(II) phospho-polymethacrylate, a synthetic analog of sandcastle worm adhesive phosphoproteins

Song, In Taek,Stewart, Russell J.

, p. 379 - 386 (2018)

The highly phosphorylated Pc3 proteins, major components of the sandcastle worm adhesive, are sequestered with Mg as spherical sub-granules within heterogeneous secretory granules in adhesive gland cells. The phase behavior of a synthetic phospho-polymethacrylate analog of the Pc3 phosphoproteins, in the presense of Mg(ii), was characterized to determine whether it is chemically possible for the natural adhesive components to be packaged and stored as liquid complex coacervates. Of several multivalent metal salts tested, only MgCl induced complex coacervation of the phospho-copolymer. Complex coacervates formed at Mg/P ratios from 0.5-8, and in [NaCl]s from 0-3 M. At low temperature and pH, the complex coacervates were clear and homogeneous. At higher temperatures and pH, the coacervate phases were translucent. The elastic and viscous moduli initially decreased as temperature increased, but then increased significantly near the temperature boundary between clear and translucent forms. A mechanism is proposed in which relatively weak, ionic strength-independent, outer shell crossbridging of -PO32- sidechains by Mg[H2O]62+ complex ions is responsible for the clear homogeneous lower viscosity coacervate form. At higher temperature and pH, displacement of inner shell H2O molecules by phosphate O- ligands creates stronger crossbridges, additional dehydration, and more viscous coacervates. The results demonstrate that Pc3 phosphoproteins can exist as condensed phospho/Mg(ii) complex coacervates under conditions expected in the adhesive glands of sandcastle worms in their natural environment. Considering the common regulatory role of phosphorylation and the intracellular abundance of Mg2+ it is possible that soft bridging of phosphate groups by Mg[H2O]n2+ may promote other regulated cellular liquid liquid phase separation phenomena.

NON-HALOGEN FLAME RETARDANT POLYMERS

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Paragraph 0098, (2017/01/12)

Non-halogenated monomers that can be polymerized into flame retardant polymers, and processes to produce the monomers and polymers is provided. In a simplest aspect, there is provided a monomer composition that can comprise a) a group derived from one of a (meth)acrylic acid, (meth)acrylamide, or vinylbenzene, b) a polyphosphate moiety, and c) an amine species. In the monomer composition, the ethylenically unsaturated monomer of (a) is covalently bonded directly or through a linking group to the moiety of b), forming a precursor monomer unit. The amine species of c) is in complex with the precursor monomer unit. The polymer can be a homopolymer of the monomer composition, or a copolymer of the monomer composition having varying a), b) and c). In one embodiment, the polymer can additionally comprise ethylenically unsaturated monomers not covalently bonded to a polyphosphate moiety and/or can be cross-linked with a cross-linking agent such as resorcinol.

COPOLYMER FOR COSMETICS, SURFACE TREATMENT AGENT FOR COSMETIC POWDER, POWDER FOR COSMETICS, AND COSMETIC PREPARATION

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Paragraph 0069, (2014/08/19)

The purpose of the present invention is to provide: a copolymer for cosmetics, which has excellent water repellency and oil repellency even though a polyfluoroalkyl group therein has 6 or less carbon atoms; a surface treatment agent which contains the copolymer for cosmetics; a powder for cosmetics, which is treated with the surface treatment agent and has excellent water repellency and oil repellency; and a cosmetic preparation which contains the powder for cosmetics. A copolymer for cosmetics of the present invention contains: 70-90% by mass of a constituent unit (A) that is derived from a compound represented by formula (a); 2-25% by mass of a constituent unit (B) that is derived from a compound represented by formula (b); 2-25% by mass of a constituent unit (C) that is derived from a compound represented by formula (c); 0.1-10% by mass of a constituent unit (D) that is derived from a compound represented by formula (d); and a residue (E) of a chain-transfer agent (e) that contains an OH group or a COOH group. [in-line-formulae]CH2═CR1—COO-Q1-Rf??(a)[/in-line-formulae] [in-line-formulae]CH2═CR2-Q2-COOH??(b)[/in-line-formulae] [in-line-formulae]CH2═CR3—COO—(R4O)n-R5??(c)[/in-line-formulae] [in-line-formulae]CH2═CR7—COO-Q3-P(O)(OH)—R8??(d)[/in-line-formulae]

DENTAL COMPOSITIONS AND METHODS WITH ARYLSULFINATE SALTS

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Page/Page column 48, (2008/06/13)

Polymerizable compositions and methods are provided that include an ethylenically unsaturated compound and an arylsulfinate salt. The polymerizable compositions are useful as hardenable dental compositions.

Acid-reactive dental fillers, compositions, and methods

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Page/Page column 14, (2010/02/14)

Acid-reactive dental fillers, and methods of making and using such fillers, are disclosed. The acid-reactive dental fillers include a trivalent metal, oxygen, fluorine, an alkaline earth metal, and, optionally, silicon. The acid-reactive dental fillers are preferably nanostructured, for example, in the form of nanoparticles.

SELF-ETCHING DENTAL COMPOSITIONS AND METHODS

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Page/Page column 42, (2008/06/13)

The present invention is directed to dental compositions that can be used as adhesives for bonding a dental material to a dental structure surface and/or as a dental restorative material. The dental composition is preferably applied to a dental structure surface under conditions effective to etch the dental structure surface.

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