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868-77-9

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Product FOB Price Min.Order Supply Ability Supplier
high purity 2-Hydroxyethyl methacrylate(868-77-9), main manufacture products, stock
Cas No: 868-77-9
USD $ 1.9-2.5 / Kilogram 1 Kilogram 999999 Kilogram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
2-Hydroxyethyl methacrylate
Cas No: 868-77-9
No Data 400 Kilogram 100 Metric Ton/Day ShangHai Jin Dun Industrial CO., LTD Contact Supplier
2-Hydroxyethyl methacrylate
Cas No: 868-77-9
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
Lower price 2-Hydroxyethyl methacrylate
Cas No: 868-77-9
USD $ 3.0-5.0 / Gram 100 Gram 200 Metric Ton/Month Hangzhou Lingrui Chemical Co.,Ltd. Contact Supplier
High quality 2-Hydroxyethyl Methacrylate ( Hema ) supplier in China
Cas No: 868-77-9
No Data 1 Kilogram 100 Metric Ton/Month Simagchem Corporation Contact Supplier
2-Hydroxyethyl methacrylate (HEMA)
Cas No: 868-77-9
USD $ 14.0-14.0 / Kilogram 1 Kilogram 500 Metric Ton/Year Jinan Finer Chemical Co., Ltd Contact Supplier
2-Hydroxyethyl methacrylate CAS NO.868-77-9
Cas No: 868-77-9
USD $ 2200.0-2300.0 / Metric Ton 1 Metric Ton 10 Metric Ton/Month Hebei yanxi chemical co.,LTD. Contact Supplier
Good quality 2-Hydroxyethyl methacrylate//cas 868-77-9
Cas No: 868-77-9
No Data 1 Metric Ton 2000 Metric Ton/Month Hefei TNJ chemical industry co.,ltd Contact Supplier
2-Hydroxyethyl Methacrylate (stabilized with MEHQ)
Cas No: 868-77-9
No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
Hydroxyethyl methacrylate
Cas No: 868-77-9
USD $ 1.5-2.0 / Kilogram 1 Kilogram 100 Metric Ton/Day EAST CHEMSOURCES LIMITED Contact Supplier

868-77-9 Usage

Uses

Used for preparation of hydrophilic polymers for biomedical devices.

Definition

ChEBI: An enoate ester that is the monomethacryloyl derivative of ethylene glycol.

Purification Methods

Dissolve the ester in water and extract with n-heptane to remove ethylene glycol dimethacrylate (checked by gas-liquid chromatography and by NMR) and distil it twice under reduced pressure [Strop et al. J Phys Chem 80 694 1976]. [Beilstein 2 IV 1530.]

Chemical Properties

colourless liquid
InChI:InChI=1/C6H10O3/c1-4(2)6(8)9-5(3)7/h5,7H,1H2,2-3H3

868-77-9 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (128635)  2-Hydroxyethylmethacrylate  contains ≤250 ppm monomethyl ether hydroquinone as inhibitor, 97% 868-77-9 128635-18KG 5,039.19CNY Detail
Aldrich (128635)  2-Hydroxyethylmethacrylate  contains ≤250 ppm monomethyl ether hydroquinone as inhibitor, 97% 868-77-9 128635-1KG 478.53CNY Detail
Aldrich (128635)  2-Hydroxyethylmethacrylate  contains ≤250 ppm monomethyl ether hydroquinone as inhibitor, 97% 868-77-9 128635-500G 407.16CNY Detail
Aldrich (477028)  2-Hydroxyethylmethacrylate  ≥99%, contains ≤50 ppm monomethyl ether hydroquinone as inhibitor 868-77-9 477028-100ML 610.74CNY Detail
Aldrich (477028)  2-Hydroxyethylmethacrylate  ≥99%, contains ≤50 ppm monomethyl ether hydroquinone as inhibitor 868-77-9 477028-25ML 542.88CNY Detail
Alfa Aesar (B24260)  2-Hydroxyethyl methacrylate, 97%, stab. with 4-methoxyphenol    868-77-9 500g 331.0CNY Detail
Alfa Aesar (B24260)  2-Hydroxyethyl methacrylate, 97%, stab. with 4-methoxyphenol    868-77-9 100g 197.0CNY Detail
TCI America (M0085)  2-Hydroxyethyl Methacrylate (stabilized with MEHQ)  >95.0%(GC) 868-77-9 500g 290.00CNY Detail
TCI America (M0085)  2-Hydroxyethyl Methacrylate (stabilized with MEHQ)  >95.0%(GC) 868-77-9 25g 120.00CNY Detail

868-77-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Nov 28, 2017

Revision Date: Nov 28, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-hydroxyethyl methacrylate

1.2 Other means of identification

Product number -
Other names 2-Hydroxyethyl methacrylate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.Adhesives and sealant chemicals,Intermediates,Paint additives and coating additives not described by other categories,Photosensitive chemicals
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:868-77-9 SDS

868-77-9Synthetic route

ethylene glycol
107-21-1

ethylene glycol

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

A

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

B

EDMA
97-90-5

EDMA

Conditions
ConditionsYield
With 10H-phenothiazine; toluene-4-sulfonic acid at 100℃; for 2.5h; Temperature; Time;A 97.18%
B 2.82%
oxirane
75-21-8

oxirane

poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
4-hydroxy-TEMPO benzoate at 100℃; for 4h;95%
With water; triethylamine at 125℃;
With pyridine; copper diacetate
oxirane
75-21-8

oxirane

poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

A

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

B

2-(2-hydroxyethoxy)ethyl methacrylate
2351-43-1

2-(2-hydroxyethoxy)ethyl methacrylate

Conditions
ConditionsYield
With triethanolamine; poly(ferric methacrylate); choline chloride In water at 30 - 66℃; for 5.53h;A 93.9%
B n/a
2-methyllactic acid
594-61-6

2-methyllactic acid

ethylene glycol
107-21-1

ethylene glycol

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
calcinated cesium carbonate and titan oxide on silica at 320℃; Gas phase;90.4%
calcinated cesium nitrate on silica In water at 320℃; Gas phase;89.2%
at 320℃; Gas phase;88%
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

ethylene glycol
107-21-1

ethylene glycol

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
With iodine for 4h; Reflux;85%
With toluene-4-sulfonic acid In benzene Heating;
methyl 2-hydroxy-2-methylpropionate
2110-78-3

methyl 2-hydroxy-2-methylpropionate

ethylene glycol
107-21-1

ethylene glycol

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
calcinated cesium nitrate on silica at 330℃; Gas phase;62.9%
2-ethylhexyl α-hydroxyisobutyrate

2-ethylhexyl α-hydroxyisobutyrate

ethylene glycol
107-21-1

ethylene glycol

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
calcinated cesium nitrate on silicate at 340℃; Gas phase;58.7%
ethylene glycol
107-21-1

ethylene glycol

ethyl 2-hydroxy-2,2-dimethylethanoate
80-55-7

ethyl 2-hydroxy-2,2-dimethylethanoate

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
calcinated cesium nitrate on silicate Gas phase;54.9%
1,2-propanediene
463-49-0

1,2-propanediene

carbon monoxide
201230-82-2

carbon monoxide

ethylene glycol
107-21-1

ethylene glycol

A

2,2-dimethyl-1,3-dioxolane
2916-31-6

2,2-dimethyl-1,3-dioxolane

B

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
dodecacarbonyl-triangulo-triruthenium at 100℃; for 3h;A 52%
B 8%
ethylene glycol
107-21-1

ethylene glycol

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
With toluene-4-sulfonic acid at 170℃;
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

2-chloro-ethanol
107-07-3

2-chloro-ethanol

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
With sodium carbonate; copper(l) chloride
potassium methacrylate
6900-35-2

potassium methacrylate

2-chloro-ethanol
107-07-3

2-chloro-ethanol

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
With copper(l) chloride
1-methacryloyloxy-2-vinyloxy-ethane

1-methacryloyloxy-2-vinyloxy-ethane

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
With sulfuric acid
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

ethylene dioxide

ethylene dioxide

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
With iron tris-<2-chloro ethylate>; iron(III) chloride
With pyridine; benzene
With sodium methylate
With iron tris-<2-chloro ethylate>; iron(III) chloride
2-chloro-ethanol
107-07-3

2-chloro-ethanol

potassium methacrylate

potassium methacrylate

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
With hydroquinone at 105 - 108℃;
ethylene glycol
107-21-1

ethylene glycol

Methacryloyl chloride
920-46-7

Methacryloyl chloride

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
In toluene at 29.85 - 59.85℃; Kinetics; Thermodynamic data; Acylation;
10H-phenothiazine
92-84-2

10H-phenothiazine

poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

A

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

B

2-(2-hydroxyethoxy)ethyl methacrylate
2351-43-1

2-(2-hydroxyethoxy)ethyl methacrylate

C

EDMA
97-90-5

EDMA

Conditions
ConditionsYield
chromium(II) acetate at 70℃; under 7500.75 Torr; for 5.5h;
oxirane
75-21-8

oxirane

poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

A

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

B

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

C

2-(2-hydroxyethoxy)ethyl methacrylate
2351-43-1

2-(2-hydroxyethoxy)ethyl methacrylate

D

EDMA
97-90-5

EDMA

Conditions
ConditionsYield
10H-phenothiazine; chromium(lll) acetate at 60 - 80℃; under 750.075 Torr; for 6.1h; Autoclave;A 96.0 %Chromat.
B 0.3 %Chromat.
C 3.7 %Chromat.
D 0.08 %Chromat.
2,4-toluene

2,4-toluene

polydiethylene hexamethylenedicarbamate

polydiethylene hexamethylenedicarbamate

ethylene glycol
107-21-1

ethylene glycol

dianhydride of benzophenone-3,4,3',4'-tetracarboxy acid
2421-28-5

dianhydride of benzophenone-3,4,3',4'-tetracarboxy acid

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
stannous octoate; hydroquinone In tetrahydrofuran
oxirane
75-21-8

oxirane

poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

A

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

B

EDMA
97-90-5

EDMA

Conditions
ConditionsYield
With 4-methoxy-phenol; chromium silicylate at 80℃; for 3h; autoclave;
With triethanolamine; poly(ferric methacrylate); choline chloride In water at 30 - 66℃; for 5.95h;A 90.9 %Chromat.
B n/a
methanol
67-56-1

methanol

C26H59NO10P2Si4
1279116-11-8

C26H59NO10P2Si4

A

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

B

C14H27NO10P2
1279116-04-9

C14H27NO10P2

C

6-hexanoic acid

6-hexanoic acid

Conditions
ConditionsYield
at 20℃; for 2h;
methanol
67-56-1

methanol

C31H69NO10P2Si4
1279116-12-9

C31H69NO10P2Si4

A

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

B

iminobis(methylenephosphono)undecanoic acid

iminobis(methylenephosphono)undecanoic acid

C

C19H37NO10P2
1279116-05-0

C19H37NO10P2

Conditions
ConditionsYield
at 20℃; for 2h;
C18H35NO10P2
1279115-96-6

C18H35NO10P2

A

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

B

6-hexanoic acid

6-hexanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: chloroform / 16 h / 20 °C
2: 2 h / 20 °C
View Scheme
C23H45NO10P2
1279115-97-7

C23H45NO10P2

A

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

B

C19H37NO10P2
1279116-05-0

C19H37NO10P2

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: chloroform / 16 h / 20 °C
2: 2 h / 20 °C
View Scheme
2-acetoxyethyl methylacrylate
20166-49-8

2-acetoxyethyl methylacrylate

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
With methanol at 20℃; for 4h;
2,2-(2-nitro-1,4-phenylene)bis(methylene)bis(oxy) bis(oxomethylene)bis(oxy)bis(ethane-2,1-diyl) bis(2-methylacrylate)
1269794-11-7

2,2-(2-nitro-1,4-phenylene)bis(methylene)bis(oxy) bis(oxomethylene)bis(oxy)bis(ethane-2,1-diyl) bis(2-methylacrylate)

A

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

B

C15H15NO7

C15H15NO7

Conditions
ConditionsYield
In tetrahydrofuran for 10h; Kinetics; UV-irradiation;
2-(methacryloyloxy)ethyl acetoacetate
21282-97-3

2-(methacryloyloxy)ethyl acetoacetate

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

Conditions
ConditionsYield
With water at 90℃; for 54h; Reactivity;
2-(methacryloyloxy)ethyl acetoacetate
21282-97-3

2-(methacryloyloxy)ethyl acetoacetate

A

2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With water at 90℃; for 54h; Reactivity;
2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

2-[(methylsulfonyl)oxy]ethyl 2-methylacrylate
16081-17-7

2-[(methylsulfonyl)oxy]ethyl 2-methylacrylate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 4.5h;100%
With triethylamine In diethyl ether at 0 - 5℃; for 0.25h;90.5%
With triethylamine In tetrahydrofuran at 0 - 20℃;37.5 g
2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

succinic acid anhydride
108-30-5

succinic acid anhydride

2-methacryloyloxyethyl hydrogen succinate
20882-04-6

2-methacryloyloxyethyl hydrogen succinate

Conditions
ConditionsYield
With 4-methoxy-phenol at 90℃; for 18h;100%
With 4-methoxy-phenol In neat (no solvent) at 90℃; for 18h; Inert atmosphere; Sealed tube;100%
With pyridine; dmap In tetrahydrofuran at 20 - 40℃; for 24h; Schlenk technique; Inert atmosphere;95%
2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

polymer; monomers: 2-hydroxyethyl methacrylate; methyl methacrylate

polymer; monomers: 2-hydroxyethyl methacrylate; methyl methacrylate

Conditions
ConditionsYield
2,2'-azobis(isobutyronitrile) In butanone at 64.85℃; for 4h; Activation energy; Kinetics; Product distribution; Further Variations:; Temperatures; times; Polymerization;100%
2,2'-azobis(isobutyronitrile) In butanone at 64.85℃; for 4h; Polymerization;100%

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