246039-81-6

Basic information

• Product Name: (+)-(2S,3R)-2-hydroxymethyl-3-methyl-1-methylidene-3-p-tolyl-cyclopentane
• CAS NO: 246039-81-6
• Molecular Weight: 216.323
• Mol File: 246039-81-6.mol

Chemical Properties

• CAS DataBase Reference: (+)-(2S,3R)-2-hydroxymethyl-3-methyl-1-methylidene-3-p-tolyl-cyclopentane(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(2S,3R)-2-hydroxymethyl-3-methyl-1-methylidene-3-p-tolyl-cyclopentane(246039-81-6)
• EPA Substance Registry System: (+)-(2S,3R)-2-hydroxymethyl-3-methyl-1-methylidene-3-p-tolyl-cyclopentane(246039-81-6)

Safety Data

• Hazardous Substances Data: 246039-81-6(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 246039-75-8 trimethyl<(3-methyl-3-p-tolyl-cyclopent-1-en-1-yl)methyl>silane 
• 108-05-4 vinyl acetate 
• 246039-74-7 diethyl(3-methyl-3-p-tolyl-cyclopent-1-en-1-yl)phosphoric triester 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 2758-18-1 3-Methyl-2-cyclopenten-1-one 

Downstream Products

• 18452-41-0 (+)-laurene 
• 246039-83-8 (+)-(2S,3R)-2-<(methanesulfonyl)-oxy>methyl-3-methyl-1-methylidene-3-p-tolyl-cyclopentane 

Relevant articles and documents

Enantiospecific total synthesis of both enantiomers of laurene by a chemical diastereoselection/lipase-catalyzed kinetic resolution sequence

A short and efficient enantiospecific total synthesis of natural (+)- laurene and its enantiomer is described. The methodology was developed by employing a stereoselective H-ene reaction of an isocyclic allyltrimethylsilane with paraformaldehyde, followed by a lipase-mediated kinetic resolution of the racemic key intermediate.