24686-80-4Relevant academic research and scientific papers
Alkoxide activation of aminoboranes towards selective amination
Sole, Cristina,Fernandez, Elena
supporting information, p. 11351 - 11355 (2013/11/06)
Piece of the (inter)action: The interaction of alkoxides with the sp 2 Bpin (pin=pinacol) moiety in aminoboranes forms the in situ Lewis acid-base adduct [RO-→B(OR)2-N(R′)2] which enables the amino moiety to react as a strong nucleophile with several electrophiles, thus providing amino alcohols, β-enamino esters, and β-hydroxy amides in a direct and remarkably selective way (see scheme). Copyright
Ni(ii) and Pd(ii) pyridinyloxazolidine-compounds: Synthesis, X-ray characterisation and catalytic activities in the aza-Michael reaction
Ardizzoia, G. Attilio,Brenna, Stefano,Therrien, Bruno
experimental part, p. 783 - 790 (2012/02/05)
The 3-phenyl-2-(pyridin-2-yl)oxazolidine ligand (ppo) was synthesised and its coordination behaviour regarding Ni(ii) and Pd(ii) centres was studied. The reaction with K2PdCl4 affords [Pd(N,N′-ppo)Cl 2] (1), in which ppo b
