247039-15-2

Basic information

• Product Name: [((3-tert-butyl-2-hydroxy-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane)ZnI₂] * CH₂Cl₂
• CAS NO: 247039-15-2
• Molecular Weight: 770.638
• Mol File: 247039-15-2.mol

Chemical Properties

• CAS DataBase Reference: [((3-tert-butyl-2-hydroxy-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane)ZnI₂] * CH₂Cl₂(CAS DataBase Reference)
• NIST Chemistry Reference: [((3-tert-butyl-2-hydroxy-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane)ZnI₂] * CH₂Cl₂(247039-15-2)
• EPA Substance Registry System: [((3-tert-butyl-2-hydroxy-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane)ZnI₂] * CH₂Cl₂(247039-15-2)

Safety Data

• Hazardous Substances Data: 247039-15-2(Hazardous Substances Data)

Upstream product

• 247039-16-3 [((3-tert-butyl-2-oxy-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane)ZnI] 
• 10034-85-2 hydrogen iodide 
• 237422-65-0 (3-tert-butyl-2-hydroxy-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane 
• 10139-47-6 zinc(II) iodide 

Relevant articles and documents

Synthesis and characterization of pseudotetrahedral N2O and N2S zinc(II) complexes of two heteroscorpionate ligands: Models for the binding sites of several zinc metalloproteins

Nine new pseudotetrahedral Zn(II) complexes of the heteroscorpionate ligands (3-tert-butyl-2-hydroxy(or thio)-5-methylphenyl)bis(3,5-dimethylpyrazolyl)methane, L1OH or L2SH, have been prepared and characterized (in most cases crystallographically). Complexes isolated include [(L1O)ZnCl], [(L1O)ZnI], [(L1OH)ZnI2], [(L1O)ZnCH3], [(L1O)ZnOAc], [(L1O)ZnSPh], [(L1O)ZnSBz], [(L2S)ZnCH3], [(L2S)ZnSPh], and [(L2S)2Zn]. In conjunction with the widely studied tris(pyrazolyl)borates this new series of heteroscorpionates provides a set of isolobal and isoelectronic ligands differing in donor set, i.e. N3, N2O, and N2S. Preliminary reactivity studies with HX species, MeI, or trimethyl phosphate suggest differences between the three sets of ligands.