24719-68-4Relevant academic research and scientific papers
Synthesis of Tetrathiafulvalene Derivatives by the Usa of Organoaluminium Reagents
Mori, Takehiko,Inokuchi, Hiroo
, p. 1873 - 1876 (1992)
Bis(dimethylaluminium) salts of ethanedithiol, 1,2-benzenedithiol, and ethylenedithiol react with 1,3-dithiolane-2-carboxylate esters to give dihydro- and tetrahydro-tetrathiafulvalenes as well as tetrathiafulvalene derivatives.
Crown Ether Annelated Tetrathiafulvalenes. 2
Hansen, T. K.,Joergensen, T.,Jensen, F.,Thygesen, P. H.,Christiansen, K.,et al.
, p. 1359 - 1366 (2007/10/02)
A synthetic procedure leading to derivatives of tetrathiafulvalene (TTF) incorporating polyether chains of various lengths, some nitrogen analogs, and a 2,6-bis(methylene)pyridine analog has been developed.These compounds possess cage-type structures which were confirmed by X-ray crystallography in four cases, two of which are reported herein for the first time.Structural and electronic features of these cage molecules were correlated to oxidation potentials by the use of semiempirical methods (MNDO-PM3).An investigation of the alkali metal ion affinity using PDMS revealed that these compounds are poor ligands.Finally, in one case, protonation of the core TTF was studied by NMR.
Chalcogenation of Tetrathiafulvalene (TTF): Synthesis of Alkylthio-TTF and Alkylseleno-TTF Derivatives and X-Ray Crystal Structure of Ethylenediseleno-TTF (EDS-TTF)
Moore, Adrian J.,Bryce, Martin R.,Cooke, Graeme,Marshallsay, Gary J.,Skabara, Peter J.,et al.
, p. 1403 - 1410 (2007/10/02)
The reaction of mono-lithiated tetrathiafulvalene (TTF) with elemental sulfur or elemental selenium at -78 deg C yields the transient species TTF-S(1-) Li(1+) and TTF-Se(1-) Li(1+), respectively, which have been trapped with a range of alkyl halides to yi
