24735-54-4Relevant academic research and scientific papers
Synthesis and Properties of 1-Acyl Triazenes
Landman, Iris R.,Acu?a-Bolomey, Emilio,Scopelliti, Rosario,Fadaei-Tirani, Farzaneh,Severin, Kay
, p. 6408 - 6412 (2019)
1-Acyl triazenes can be prepared by acid-catalyzed hydration, gold/iodine-catalyzed oxidation, or oxyhalogenation of 1-alkynyl triazenes. Crystallographic analyses reveal a pronounced effect of the acyl group on the electronic structure of the triazene fu
OXIDATIVE KUPPLUNG VON 1,2-DIENEN MIT ISOCYANATEN AM LIG-NICKEL(0)-SYSTEM
Hoberg, Heinz,Suemmermann, Klaus
, p. 239 - 248 (2007/10/02)
Isocyanates undergo a 1/1 oxidative coupling reaction with 1,2-dienes and Lig-Ni0 systems to give azanickelacyclopentanones.The coupling to form the nickela complexes proceeds in such a way that the exo-methylene group is conjugated with the carbonyl group.The influence of the ligands and the temperature on the regioselectivity of the C-C coupling is reported.
